Identification of a sex pheromone component of Pseudococcus cryptus

Tomonori Arai, Hajime Sugie, Syuntaro Hiradate, Shigefumi Kuwahara, Noriaki Itagaki, Takashi Nakahata

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)


A sex pheromone component of Pseudococcus cryptus has been isolated and identified. The crude pheromone extract obtained by airborne collection was fractionated by liquid chromatography (LC) on Florisil, and further purified by high performance liquid chromatography and preparative Gas Chromatography (GC). The pheromone component was shown to be an ester, the alcohol part of which was identical to the known alcohol moiety of the pheromone of Planococcus citri. The chemical structure was determined to be 3-isopropenyl-2,2-dimethylcyclobutylmethyl 3-methyl-3-butenoate by MS and 1H NMR analyses. The absolute configuration of the pheromone was assigned as (1R,3R) by comparison of the retention time of the alcohol derived from the P. cryptus pheromone with those of the alcohol derived from P. citri pheromone, and a synthetic sample of alcohol enriched in the (1R,3R)-enantiomer, using a chiral GC stationary phase. The structure of the pheromone was confirmed by synthesis, and by bioassays in a glasshouse.

Original languageEnglish
Pages (from-to)2213-2223
Number of pages11
JournalJournal of Chemical Ecology
Issue number10
Publication statusPublished - Oct 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Ecology, Evolution, Behavior and Systematics
  • Biochemistry


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