Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes

Hiroshi Aoyama; Makoto Tokunaga; Shin Ichiro Hiraiwa; Yuki Shirogane; Yasushi Obora; Yasushi Tsuji

doi:10.1021/ol036228j

Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes

Hiroshi Aoyama, Makoto Tokunaga, Shin Ichiro Hiraiwa, Yuki Shirogane, Yasushi Obora, Yasushi Tsuji

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

(Equation presented) Various kinds of transition metals catalyzed the hydrolysis of alkenyl esters and ethers under buffer-free, high concentration conditions compared to usual biocatalysts. Hydrolytic kinetic resolution of cis-2-tert-butylcyclohexyl vinyl ether was achieved by chiral (salen)Co complexes with good selectivity (k_rel = 10.0).

Original language	English
Pages (from-to)	509-512
Number of pages	4
Journal	Organic letters
Volume	6
Issue number	4
DOIs	https://doi.org/10.1021/ol036228j
Publication status	Published - Feb 19 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol036228j

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abstract = "(Equation presented) Various kinds of transition metals catalyzed the hydrolysis of alkenyl esters and ethers under buffer-free, high concentration conditions compared to usual biocatalysts. Hydrolytic kinetic resolution of cis-2-tert-butylcyclohexyl vinyl ether was achieved by chiral (salen)Co complexes with good selectivity (krel = 10.0).",

author = "Hiroshi Aoyama and Makoto Tokunaga and Hiraiwa, {Shin Ichiro} and Yuki Shirogane and Yasushi Obora and Yasushi Tsuji",

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AU - Aoyama, Hiroshi

AU - Tokunaga, Makoto

AU - Hiraiwa, Shin Ichiro

AU - Shirogane, Yuki

AU - Obora, Yasushi

AU - Tsuji, Yasushi

PY - 2004/2/19

Y1 - 2004/2/19

N2 - (Equation presented) Various kinds of transition metals catalyzed the hydrolysis of alkenyl esters and ethers under buffer-free, high concentration conditions compared to usual biocatalysts. Hydrolytic kinetic resolution of cis-2-tert-butylcyclohexyl vinyl ether was achieved by chiral (salen)Co complexes with good selectivity (krel = 10.0).

AB - (Equation presented) Various kinds of transition metals catalyzed the hydrolysis of alkenyl esters and ethers under buffer-free, high concentration conditions compared to usual biocatalysts. Hydrolytic kinetic resolution of cis-2-tert-butylcyclohexyl vinyl ether was achieved by chiral (salen)Co complexes with good selectivity (krel = 10.0).

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Hydrolysis of Alkenyl Esters and Ethers Catalyzed by Metal Complexes

Abstract

All Science Journal Classification (ASJC) codes

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