TY - JOUR
T1 - H2 and O2 activation - A remarkable insight into hydrogenase
AU - Ogo, Seiji
N1 - Funding Information:
This work was supported by the National Natural Science Foundation of China (51368044, 51568051, 51668046), the National Science Fund for Excellent Young Scholars (51422807), the Science and Technology Supporting Program of Jiangxi Province (20151BBG70018), the Natural Science Foundation of Jiangxi Province for Distinguished Young Scholars (20162BCB23041), the Science Foundation for Young Scientists of Jiangxi Province-Key Project (20171ACB21034), the Science and Technology Project of Jiangxi Provincial Education Department (GJJ160700), the Natural Science Foundation of Jiangxi Province (20161BAB216102), the Jiangxi Province Educational Reform Project (JXJG-16-8-7), and the Nanchang Hangkong University Educational Reform Project (JY1604, JY1605, KCPY-1511).
PY - 2014/6
Y1 - 2014/6
N2 - This article summarizes the development of a range of organometallic, biomimetic analogues of [NiFe]hydrogenases and their employment in a new generation of H2-O2 fuel cells. It begins with a summary of O2-sensitive and O2-tolerant enzyme chemistry before detailing the properties and functionality of our biomimetic complexes, including: the first ever fully functional model, selective H2 and O2 activation, and the first catalyst using only common metals. These systems are centered on Ni-Fe, Ni-Ru, Ir-Ir, and Rh-Rh cores and use a range of ligands that all follow a set of design principles described herein. The development of a range of organometallic, biomimetic analogues of [NiFe]hydrogenases and their employment in a new generation of H 2-O2 fuel cells are described. This account begins with a summary of O2-sensitive and O2-tolerant enzyme chemistry before detailing the properties and functionality of our biomimetic complexes, including: the first ever fully functional model, selective H2 and O2 activation, and the first catalyst using only common metals.
AB - This article summarizes the development of a range of organometallic, biomimetic analogues of [NiFe]hydrogenases and their employment in a new generation of H2-O2 fuel cells. It begins with a summary of O2-sensitive and O2-tolerant enzyme chemistry before detailing the properties and functionality of our biomimetic complexes, including: the first ever fully functional model, selective H2 and O2 activation, and the first catalyst using only common metals. These systems are centered on Ni-Fe, Ni-Ru, Ir-Ir, and Rh-Rh cores and use a range of ligands that all follow a set of design principles described herein. The development of a range of organometallic, biomimetic analogues of [NiFe]hydrogenases and their employment in a new generation of H 2-O2 fuel cells are described. This account begins with a summary of O2-sensitive and O2-tolerant enzyme chemistry before detailing the properties and functionality of our biomimetic complexes, including: the first ever fully functional model, selective H2 and O2 activation, and the first catalyst using only common metals.
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U2 - 10.1002/tcr.201402010
DO - 10.1002/tcr.201402010
M3 - Article
AN - SCOPUS:84903214636
SN - 1527-8999
VL - 14
SP - 397
EP - 409
JO - Chemical Record
JF - Chemical Record
IS - 3
ER -