Homo- and heterobismetal complexes of 5-hydroxy- (pentafIuorophenyl)-substituted [26]hexaphyrin(

Taro Koide, Gengo Kashiwazaki, Ko Furukawa, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)


Metalation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin( (4) with CuII and ZnII ions afforded homodinuclear complexes 6 and 7, respectively. A demetalation- remetalation protocol provided monozinc(II) complex 9 selectively, from which copper(II) - zinc(II) heterodi-nuclear complex 10 was prepared effectively.

Original languageEnglish
Pages (from-to)4595-4597
Number of pages3
JournalInorganic chemistry
Issue number11
Publication statusPublished - Jun 1 2009
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry


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