Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative

Keisuke Suzuki; Eiji Katayama; Katsuhiko Tomooka; Takashi Matsumoto; Gen ichi Tsuchihashi

doi:10.1016/S0040-4039(00)89229-1

Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative

Keisuke Suzuki, Eiji Katayama, Katsuhiko Tomooka, Takashi Matsumoto, Gen ichi Tsuchihashi

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

All four diastereomere of chiral alcohol 2 with three contiguous chiral centers were stereoselectively prepared via diastereoselective addition of nucleophiles (crotyl metal or H^-) to α-methyl-β,γ-unsaturated carbonyl compounds 1.

Original language	English
Pages (from-to)	3707-3710
Number of pages	4
Journal	Tetrahedron Letters
Volume	26
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(00)89229-1
Publication status	Published - Jan 1 1985
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Organic Chemistry
Drug Discovery

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10.1016/S0040-4039(00)89229-1

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Suzuki, K., Katayama, E., Tomooka, K., Matsumoto, T., & Tsuchihashi, G. I. (1985). Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative. Tetrahedron Letters, 26(31), 3707-3710. https://doi.org/10.1016/S0040-4039(00)89229-1

Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative. / Suzuki, Keisuke; Katayama, Eiji; Tomooka, Katsuhiko et al.
In: Tetrahedron Letters, Vol. 26, No. 31, 01.01.1985, p. 3707-3710.

Research output: Contribution to journal › Article › peer-review

Suzuki, K, Katayama, E, Tomooka, K, Matsumoto, T & Tsuchihashi, GI 1985, 'Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative', Tetrahedron Letters, vol. 26, no. 31, pp. 3707-3710. https://doi.org/10.1016/S0040-4039(00)89229-1

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abstract = "All four diastereomere of chiral alcohol 2 with three contiguous chiral centers were stereoselectively prepared via diastereoselective addition of nucleophiles (crotyl metal or H-) to α-methyl-β,γ-unsaturated carbonyl compounds 1.",

author = "Keisuke Suzuki and Eiji Katayama and Katsuhiko Tomooka and Takashi Matsumoto and Tsuchihashi, {Gen ichi}",

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AU - Matsumoto, Takashi

AU - Tsuchihashi, Gen ichi

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Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative

Abstract

All Science Journal Classification (ASJC) codes

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