Guest-selective and reversible magnetic phase switching in a pseudo-pillared-layer porous magnet

Haruka Yoshino; Narumi Tomokage; Akio Mishima; Benjamin Le Ouay; Ryo Ohtani; Wataru Kosaka; Hitoshi Miyasaka; Masaaki Ohba

doi:10.1039/d1cc01526e

Guest-selective and reversible magnetic phase switching in a pseudo-pillared-layer porous magnet

Haruka Yoshino, Narumi Tomokage, Akio Mishima, Benjamin Le Ouay, Ryo Ohtani, Wataru Kosaka, Hitoshi Miyasaka, Masaaki Ohba

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A novel porous magnet consisting of cationic two-dimensional (2-D) layers extended by FeIII-CN-NiII linkages and pseudo-pillar dianions was synthesized. The size-selective guest adsorption behaviour of water and methanol molecules originates from the narrow bottle-neck-type pores in the flexible pseudo-pillared-layer structure, which results in the switching of the magnetic phases from antiferromagnetic to ferromagnetic, involving significant changes in the interlayer distance.

Original language	English
Pages (from-to)	5211-5214
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	42
DOIs	https://doi.org/10.1039/d1cc01526e
Publication status	Published - May 25 2021

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d1cc01526e

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title = "Guest-selective and reversible magnetic phase switching in a pseudo-pillared-layer porous magnet",

abstract = "A novel porous magnet consisting of cationic two-dimensional (2-D) layers extended by FeIII-CN-NiII linkages and pseudo-pillar dianions was synthesized. The size-selective guest adsorption behaviour of water and methanol molecules originates from the narrow bottle-neck-type pores in the flexible pseudo-pillared-layer structure, which results in the switching of the magnetic phases from antiferromagnetic to ferromagnetic, involving significant changes in the interlayer distance.",

author = "Haruka Yoshino and Narumi Tomokage and Akio Mishima and {Le Ouay}, Benjamin and Ryo Ohtani and Wataru Kosaka and Hitoshi Miyasaka and Masaaki Ohba",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number JP16H06519 (coordination asymmetry), JP18H01997, JP18K 14245, JP19H04701 and JP20K22554. This work was also supported by JSPS Research Fellowships for Young scientists (No. 19J12589). W. K. and H. M. are thankful for the financial support: KAKENHI (No. JP18K05055, JP18H05208, and JP20H00381), the Iketani Science and Technology Foundation and Grant for Basic Science Research Projects from the Sumitomo Foundation. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

month = may,

day = "25",

doi = "10.1039/d1cc01526e",

language = "English",

volume = "57",

pages = "5211--5214",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Guest-selective and reversible magnetic phase switching in a pseudo-pillared-layer porous magnet

AU - Yoshino, Haruka

AU - Tomokage, Narumi

AU - Mishima, Akio

AU - Le Ouay, Benjamin

AU - Ohtani, Ryo

AU - Kosaka, Wataru

AU - Miyasaka, Hitoshi

AU - Ohba, Masaaki

N1 - Funding Information: This work was supported by JSPS KAKENHI Grant Number JP16H06519 (coordination asymmetry), JP18H01997, JP18K 14245, JP19H04701 and JP20K22554. This work was also supported by JSPS Research Fellowships for Young scientists (No. 19J12589). W. K. and H. M. are thankful for the financial support: KAKENHI (No. JP18K05055, JP18H05208, and JP20H00381), the Iketani Science and Technology Foundation and Grant for Basic Science Research Projects from the Sumitomo Foundation. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/5/25

Y1 - 2021/5/25

N2 - A novel porous magnet consisting of cationic two-dimensional (2-D) layers extended by FeIII-CN-NiII linkages and pseudo-pillar dianions was synthesized. The size-selective guest adsorption behaviour of water and methanol molecules originates from the narrow bottle-neck-type pores in the flexible pseudo-pillared-layer structure, which results in the switching of the magnetic phases from antiferromagnetic to ferromagnetic, involving significant changes in the interlayer distance.

AB - A novel porous magnet consisting of cationic two-dimensional (2-D) layers extended by FeIII-CN-NiII linkages and pseudo-pillar dianions was synthesized. The size-selective guest adsorption behaviour of water and methanol molecules originates from the narrow bottle-neck-type pores in the flexible pseudo-pillared-layer structure, which results in the switching of the magnetic phases from antiferromagnetic to ferromagnetic, involving significant changes in the interlayer distance.

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U2 - 10.1039/d1cc01526e

DO - 10.1039/d1cc01526e

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AN - SCOPUS:85106654648

SN - 1359-7345

VL - 57

SP - 5211

EP - 5214

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Guest-selective and reversible magnetic phase switching in a pseudo-pillared-layer porous magnet

Abstract

All Science Journal Classification (ASJC) codes

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