Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)

Shigeki Mori; Soji Shimizu; Ji Young Shin; Atsuhiro Osuka

doi:10.1021/ic7004216

Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)

Shigeki Mori, Soji Shimizu, Ji Young Shin, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

Original language	English
Pages (from-to)	4374-4376
Number of pages	3
Journal	Inorganic chemistry
Volume	46
Issue number	11
DOIs	https://doi.org/10.1021/ic7004216
Publication status	Published - May 28 2007
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic7004216

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abstract = "Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.",

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AU - Mori, Shigeki

AU - Shimizu, Soji

AU - Shin, Ji Young

AU - Osuka, Atsuhiro

PY - 2007/5/28

Y1 - 2007/5/28

N2 - Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

AB - Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

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Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)

Abstract

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