Group 10 metal complexes of mesoaryl-substituted [26]hexaphyrins with a metal-carbon bond

Shigeki Mori; Soji Shimizu; Ryuichiro Taniguchi; Atsuhiro Osuka

doi:10.1021/ic050447e

Group 10 metal complexes of mesoaryl-substituted [26]hexaphyrins with a metal-carbon bond

Shigeki Mori, Soji Shimizu, Ryuichiro Taniguchi, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

Nickel(II), palladium(II), and platinum(II) complexes of meso-arylsubstituted [26]hexaphyrin have been prepared and structurally characterized. In mono-metalated complexes, the metal ion is commonly bound with three pyrrolic nitrogen atoms and one pyrrolic β-carbon, whereas a bis-Pd(II) complex exhibits a unique structure involving a Pd-C _α bond. These results reveal novel coordination abilities of the hexaphyrin that lead to a metal-carbon bond at either pyrrolic C _β or C_α position.

Original language	English
Pages (from-to)	4127-4129
Number of pages	3
Journal	Inorganic Chemistry
Volume	44
Issue number	12
DOIs	https://doi.org/10.1021/ic050447e
Publication status	Published - Jun 13 2005
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic050447e

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abstract = "Nickel(II), palladium(II), and platinum(II) complexes of meso-arylsubstituted [26]hexaphyrin have been prepared and structurally characterized. In mono-metalated complexes, the metal ion is commonly bound with three pyrrolic nitrogen atoms and one pyrrolic β-carbon, whereas a bis-Pd(II) complex exhibits a unique structure involving a Pd-C α bond. These results reveal novel coordination abilities of the hexaphyrin that lead to a metal-carbon bond at either pyrrolic C β or Cα position.",

author = "Shigeki Mori and Soji Shimizu and Ryuichiro Taniguchi and Atsuhiro Osuka",

year = "2005",

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T1 - Group 10 metal complexes of mesoaryl-substituted [26]hexaphyrins with a metal-carbon bond

AU - Mori, Shigeki

AU - Shimizu, Soji

AU - Taniguchi, Ryuichiro

AU - Osuka, Atsuhiro

PY - 2005/6/13

Y1 - 2005/6/13

N2 - Nickel(II), palladium(II), and platinum(II) complexes of meso-arylsubstituted [26]hexaphyrin have been prepared and structurally characterized. In mono-metalated complexes, the metal ion is commonly bound with three pyrrolic nitrogen atoms and one pyrrolic β-carbon, whereas a bis-Pd(II) complex exhibits a unique structure involving a Pd-C α bond. These results reveal novel coordination abilities of the hexaphyrin that lead to a metal-carbon bond at either pyrrolic C β or Cα position.

AB - Nickel(II), palladium(II), and platinum(II) complexes of meso-arylsubstituted [26]hexaphyrin have been prepared and structurally characterized. In mono-metalated complexes, the metal ion is commonly bound with three pyrrolic nitrogen atoms and one pyrrolic β-carbon, whereas a bis-Pd(II) complex exhibits a unique structure involving a Pd-C α bond. These results reveal novel coordination abilities of the hexaphyrin that lead to a metal-carbon bond at either pyrrolic C β or Cα position.

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Group 10 metal complexes of mesoaryl-substituted [26]hexaphyrins with a metal-carbon bond

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