Gallium(III)corrole-BODIPY hybrid: Novel photophysical properties and first observation of B-F⋯F interactions

Biju Basumatary; R. V. Ramana Reddy; Subhrajyoti Bhandary; Jeyaraman Sankar

doi:10.1039/c5dt03104d

Gallium(III)corrole-BODIPY hybrid: Novel photophysical properties and first observation of B-F⋯F interactions

Biju Basumatary, R. V. Ramana Reddy, Subhrajyoti Bhandary, Jeyaraman Sankar

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Anchoring a BODIPY onto Ga(iii)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound 4 hosts the first example of a novel B-F⋯F interaction as well.

Original language	English
Pages (from-to)	20817-20821
Number of pages	5
Journal	Dalton Transactions
Volume	44
Issue number	48
DOIs	https://doi.org/10.1039/c5dt03104d
Publication status	Published - 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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abstract = "Anchoring a BODIPY onto Ga(iii)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound 4 hosts the first example of a novel B-F⋯F interaction as well.",

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AU - Basumatary, Biju

AU - Ramana Reddy, R. V.

AU - Bhandary, Subhrajyoti

AU - Sankar, Jeyaraman

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PY - 2015

Y1 - 2015

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AB - Anchoring a BODIPY onto Ga(iii)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound 4 hosts the first example of a novel B-F⋯F interaction as well.

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ER -

Gallium(III)corrole-BODIPY hybrid: Novel photophysical properties and first observation of B-F⋯F interactions

Abstract

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