Functional group-selective poisoning of molecular catalysts: A ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters

Hidehiro Sasakuma; Yukihiro Motoyama; Hideo Nagashima

doi:10.1039/b711743d

Functional group-selective poisoning of molecular catalysts: A ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters

Hidehiro Sasakuma, Yukihiro Motoyama, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

The addition of amines eliminates the catalytic activity of a triruthenium cluster in the hydrosilane reduction of ketones and esters without affecting the rate of reduction of amides; selective reduction of the amide group in amido ketones and amido esters is accomplished.

Original language	English
Pages (from-to)	4916-4918
Number of pages	3
Journal	Chemical Communications
Issue number	46
DOIs	https://doi.org/10.1039/b711743d
Publication status	Published - 2007

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b711743d

Cite this

@article{b7002d351a9844a08af336a772736fdc,

title = "Functional group-selective poisoning of molecular catalysts: A ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters",

abstract = "The addition of amines eliminates the catalytic activity of a triruthenium cluster in the hydrosilane reduction of ketones and esters without affecting the rate of reduction of amides; selective reduction of the amide group in amido ketones and amido esters is accomplished.",

author = "Hidehiro Sasakuma and Yukihiro Motoyama and Hideo Nagashima",

year = "2007",

doi = "10.1039/b711743d",

language = "English",

pages = "4916--4918",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "46",

}

TY - JOUR

T1 - Functional group-selective poisoning of molecular catalysts

T2 - A ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters

AU - Sasakuma, Hidehiro

AU - Motoyama, Yukihiro

AU - Nagashima, Hideo

PY - 2007

Y1 - 2007

N2 - The addition of amines eliminates the catalytic activity of a triruthenium cluster in the hydrosilane reduction of ketones and esters without affecting the rate of reduction of amides; selective reduction of the amide group in amido ketones and amido esters is accomplished.

AB - The addition of amines eliminates the catalytic activity of a triruthenium cluster in the hydrosilane reduction of ketones and esters without affecting the rate of reduction of amides; selective reduction of the amide group in amido ketones and amido esters is accomplished.

UR - http://www.scopus.com/inward/record.url?scp=37549052899&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37549052899&partnerID=8YFLogxK

U2 - 10.1039/b711743d

DO - 10.1039/b711743d

M3 - Article

AN - SCOPUS:37549052899

SN - 1359-7345

SP - 4916

EP - 4918

JO - Chemical Communications

JF - Chemical Communications

IS - 46

ER -

Functional group-selective poisoning of molecular catalysts: A ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this