Formation of toxic gases during pyrolysis of polyacrylonitrile and nylons

M. Nielsen; P. Jurasek; J. Hayashi; E. Furimsky

doi:10.1016/0165-2370(95)00898-O

Formation of toxic gases during pyrolysis of polyacrylonitrile and nylons

M. Nielsen
, P. Jurasek
, J. Hayashi
, E. Furimsky

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

The FT-IR technique was found to be suitable for the rapid determination of toxic species. Formation of toxic gases such as HCN, CO and NH₃ during temperature programmed (10 °C/min) pyrolysis of polyacrylonitrile and nylon 6.6, 6.12 and 12 was determined in a fixed bed reactor. For polyacrylonitrile (PAN), HCN and NH₃ were the major toxic-products, whereas NH₃ only was the major toxic product for nylons. During pyrolysis of PAN, the yield of HCN was more than 100 times greater than that during pyrolysis of nylons. CO was formed during pyrolysis of all the tested polymers.

Original language	English
Pages (from-to)	43-51
Number of pages	9
Journal	Journal of Analytical and Applied Pyrolysis
Volume	35
Issue number	1
DOIs	https://doi.org/10.1016/0165-2370(95)00898-O
Publication status	Published - Oct 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Fuel Technology

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10.1016/0165-2370(95)00898-O

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abstract = "The FT-IR technique was found to be suitable for the rapid determination of toxic species. Formation of toxic gases such as HCN, CO and NH3 during temperature programmed (10 °C/min) pyrolysis of polyacrylonitrile and nylon 6.6, 6.12 and 12 was determined in a fixed bed reactor. For polyacrylonitrile (PAN), HCN and NH3 were the major toxic-products, whereas NH3 only was the major toxic product for nylons. During pyrolysis of PAN, the yield of HCN was more than 100 times greater than that during pyrolysis of nylons. CO was formed during pyrolysis of all the tested polymers.",

author = "M. Nielsen and P. Jurasek and J. Hayashi and E. Furimsky",

year = "1995",

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T1 - Formation of toxic gases during pyrolysis of polyacrylonitrile and nylons

AU - Nielsen, M.

AU - Jurasek, P.

AU - Hayashi, J.

AU - Furimsky, E.

PY - 1995/10

Y1 - 1995/10

N2 - The FT-IR technique was found to be suitable for the rapid determination of toxic species. Formation of toxic gases such as HCN, CO and NH3 during temperature programmed (10 °C/min) pyrolysis of polyacrylonitrile and nylon 6.6, 6.12 and 12 was determined in a fixed bed reactor. For polyacrylonitrile (PAN), HCN and NH3 were the major toxic-products, whereas NH3 only was the major toxic product for nylons. During pyrolysis of PAN, the yield of HCN was more than 100 times greater than that during pyrolysis of nylons. CO was formed during pyrolysis of all the tested polymers.

AB - The FT-IR technique was found to be suitable for the rapid determination of toxic species. Formation of toxic gases such as HCN, CO and NH3 during temperature programmed (10 °C/min) pyrolysis of polyacrylonitrile and nylon 6.6, 6.12 and 12 was determined in a fixed bed reactor. For polyacrylonitrile (PAN), HCN and NH3 were the major toxic-products, whereas NH3 only was the major toxic product for nylons. During pyrolysis of PAN, the yield of HCN was more than 100 times greater than that during pyrolysis of nylons. CO was formed during pyrolysis of all the tested polymers.

UR - https://www.scopus.com/pages/publications/0002916142

UR - https://www.scopus.com/pages/publications/0002916142#tab=citedBy

U2 - 10.1016/0165-2370(95)00898-O

DO - 10.1016/0165-2370(95)00898-O

M3 - Article

AN - SCOPUS:0002916142

SN - 0165-2370

VL - 35

SP - 43

EP - 51

JO - Journal of Analytical and Applied Pyrolysis

JF - Journal of Analytical and Applied Pyrolysis

IS - 1

ER -

Formation of toxic gases during pyrolysis of polyacrylonitrile and nylons

Abstract

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