Formation and characterization of an SH(2II 3 2, 1 2) radical beam produced by the F + H2S reaction using a sextupole electric field

T. Kasai; K. Ohashi; H. Ohoyama; K. Kuwata

doi:10.1016/0009-2614(86)80612-1

Formation and characterization of an SH(²II_{3 2, 1 2}) radical beam produced by the F + H₂S reaction using a sextupole electric field

T. Kasai, K. Ohashi, H. Ohoyama, K. Kuwata

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

An unstable free radical beam of SH was produced by the reaction of fluorine atoms with H₂S and effused from a Teflon nozzle. The beam was focused using sextupole electric fields. Monte Carlo trajectory simulations showed 300 ± 50 K as the rotational temperature for the chemically produced SH, so that an oriented SH beam with (cos θ ) = - 0.28 could be available in the presence of an intense electric field. The beam intensity of the focused SH is estimated to be about 10¹¹ molecule sr^-1 s^-1.

Original language	English
Pages (from-to)	581-584
Number of pages	4
Journal	Chemical Physics Letters
Volume	127
Issue number	6
DOIs	https://doi.org/10.1016/0009-2614(86)80612-1
Publication status	Published - Jul 4 1986
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(86)80612-1

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title = "Formation and characterization of an SH(2II 3 2, 1 2) radical beam produced by the F + H2S reaction using a sextupole electric field",

abstract = "An unstable free radical beam of SH was produced by the reaction of fluorine atoms with H2S and effused from a Teflon nozzle. The beam was focused using sextupole electric fields. Monte Carlo trajectory simulations showed 300 ± 50 K as the rotational temperature for the chemically produced SH, so that an oriented SH beam with (cos θ ) = - 0.28 could be available in the presence of an intense electric field. The beam intensity of the focused SH is estimated to be about 1011 molecule sr-1 s-1.",

author = "T. Kasai and K. Ohashi and H. Ohoyama and K. Kuwata",

year = "1986",

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doi = "10.1016/0009-2614(86)80612-1",

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T1 - Formation and characterization of an SH(2II 3 2, 1 2) radical beam produced by the F + H2S reaction using a sextupole electric field

AU - Kasai, T.

AU - Ohashi, K.

AU - Ohoyama, H.

AU - Kuwata, K.

PY - 1986/7/4

Y1 - 1986/7/4

N2 - An unstable free radical beam of SH was produced by the reaction of fluorine atoms with H2S and effused from a Teflon nozzle. The beam was focused using sextupole electric fields. Monte Carlo trajectory simulations showed 300 ± 50 K as the rotational temperature for the chemically produced SH, so that an oriented SH beam with (cos θ ) = - 0.28 could be available in the presence of an intense electric field. The beam intensity of the focused SH is estimated to be about 1011 molecule sr-1 s-1.

AB - An unstable free radical beam of SH was produced by the reaction of fluorine atoms with H2S and effused from a Teflon nozzle. The beam was focused using sextupole electric fields. Monte Carlo trajectory simulations showed 300 ± 50 K as the rotational temperature for the chemically produced SH, so that an oriented SH beam with (cos θ ) = - 0.28 could be available in the presence of an intense electric field. The beam intensity of the focused SH is estimated to be about 1011 molecule sr-1 s-1.

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SN - 0009-2614

VL - 127

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EP - 584

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

Formation and characterization of an SH(²II_{3 2, 1 2}) radical beam produced by the F + H₂S reaction using a sextupole electric field

Abstract

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