@article{35d1fcf9c16443b6838216bd4925b024,
title = "Formal nucleophilic boryl substitution of organic halides with Silylborane/Alkoxy base system",
abstract = "Boryl substitution of organohalides with a silylborane and alkoxy bases is described. This reaction can be applied to various functionalized aryl halides. Alkyl and alkenyl halides, and even sterically congested aryl bromides also provided the corresponding borylated products in high yields. Mechanistic studies indicated that neither trace transition-metal impurities nor aryl radical species involved in this reaction.",
author = "Eiji Yamamoto and Kiyotaka Izumi and Yuko Horita and Satoshi Ukigai and Hajime Ito",
note = "Funding Information: Acknowledgments We thank Prof. T. Ohkuma and Prof. N. Kurono (Hokkaido University) for conducting the independent control experiments. The Funding Program for Next Generation World-Leading Researchers (NEXT Program, GR002) and the Sasakawa Scientific Research Grant from The Japan Science Society are gratefully acknowledged. We thank the Open Facility (Sousei Hall, Hokkaido University) for allowing us to perform ICPE-9000 measurements on the ICP-AES and especially N. Takeda for her great technical assistance and helpful suggestions.",
year = "2014",
month = jun,
doi = "10.1007/s11244-014-0255-y",
language = "English",
volume = "57",
pages = "940--945",
journal = "Topics in Catalysis",
issn = "1022-5528",
publisher = "Springer Netherlands",
number = "10-13",
}