@article{7b7911dc04684f83a2e28c02e3fe610a,
title = "Force-responsive ordered carbonaceous frameworks synthesized from Ni-porphyrin",
abstract = "Force-responsive ordered carbonaceous frameworks (OCFs) are synthesized for the first time. Carbonization of Ni porphyrin monomers having eight polymerizable ethynyl groups yields OCFs with atomically dispersed divalent Ni species and developed micropores. The highest specific surface area (673 m2g−1) among the OCFs has been achieved. The OCFs thus synthesized comprise non-stacked graphene sheets, affording a unique mechanical flexibility that enables force-driven reversible phase transition.",
author = "Koki Chida and Takeharu Yoshii and Kazuma Takahashi and Masanori Yamamoto and Kazuya Kanamaru and Mao Ohwada and Varisara Deerattrakul and Jun Maruyama and Kazuhide Kamiya and Yuichiro Hayasaka and Masataka Inoue and Fumito Tani and Hirotomo Nishihara",
note = "Funding Information: This work was supported by JST CREST Grant no. JPMJCRI18R3; the {\textquoteleft}{\textquoteleft}Five-star Alliance{\textquoteright}{\textquoteright} in {\textquoteleft}{\textquoteleft}NJRC Mater. & Dev.{\textquoteright}{\textquoteright}; Japan Association for Chemical Innovation. The XAFS spectra were recorded at the BL01B1 and BL14B2 stations in SPring-8, Harima, Japan (Proposal no. 2020A1254 and 2020A1604, respectively). The authors acknowledge Prof. T. Kyotani for his advice, Prof. H. Kato for his kind support in Raman spectroscopy, Prof. Y. Nishina for his advice on catalysis, and Mr S. Yoshida for his kind support in 13C NMR measurements. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",
year = "2021",
month = jun,
day = "21",
doi = "10.1039/d1cc01618k",
language = "English",
volume = "57",
pages = "6007--6010",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "49",
}