Facile formation of N-confused porphyrin dimers by platinum(II) coordination to the outer-nitrogen atoms

Hiroyuki Furuta; Katsuyuki Youfu; Hiromitsu Maeda; Atsuhiro Osuka

doi:10.1002/anie.200350995

Facile formation of N-confused porphyrin dimers by platinum(II) coordination to the outer-nitrogen atoms

Hiroyuki Furuta, Katsuyuki Youfu, Hiromitsu Maeda, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

Confusion but no doubt: Two types of Pt^II dimer complexes of N-confused porphyrin (depicted) were synthesized and the structures were unequivocally elucidated by X-ray crystal analyses. Both complexes contain a metallocycle that binds to a Pt center by an outer-nitrogen atom of the confused porphyrin, and by an orthocarbon atom of a meso-aryl group.

Original language	English
Pages (from-to)	2186-2188
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	19
DOIs	https://doi.org/10.1002/anie.200350995
Publication status	Published - May 16 2003

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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abstract = "Confusion but no doubt: Two types of PtII dimer complexes of N-confused porphyrin (depicted) were synthesized and the structures were unequivocally elucidated by X-ray crystal analyses. Both complexes contain a metallocycle that binds to a Pt center by an outer-nitrogen atom of the confused porphyrin, and by an orthocarbon atom of a meso-aryl group.",

author = "Hiroyuki Furuta and Katsuyuki Youfu and Hiromitsu Maeda and Atsuhiro Osuka",

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AU - Furuta, Hiroyuki

AU - Youfu, Katsuyuki

AU - Maeda, Hiromitsu

AU - Osuka, Atsuhiro

PY - 2003/5/16

Y1 - 2003/5/16

N2 - Confusion but no doubt: Two types of PtII dimer complexes of N-confused porphyrin (depicted) were synthesized and the structures were unequivocally elucidated by X-ray crystal analyses. Both complexes contain a metallocycle that binds to a Pt center by an outer-nitrogen atom of the confused porphyrin, and by an orthocarbon atom of a meso-aryl group.

AB - Confusion but no doubt: Two types of PtII dimer complexes of N-confused porphyrin (depicted) were synthesized and the structures were unequivocally elucidated by X-ray crystal analyses. Both complexes contain a metallocycle that binds to a Pt center by an outer-nitrogen atom of the confused porphyrin, and by an orthocarbon atom of a meso-aryl group.

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Facile formation of N-confused porphyrin dimers by platinum(II) coordination to the outer-nitrogen atoms

Abstract

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