Facile, convenient synthesis of highly pure ω-ferrocenylalkanethiols as probes for self-assembled monolayer (sam) on gold surface

Masato Tazaki; Kenji Okada; Kenshi Yakata; Koji Nakano; Masashi Sakai; Tadashi Yonemitsu

doi:10.1080/10426500008082402

Facile, convenient synthesis of highly pure ω-ferrocenylalkanethiols as probes for self-assembled monolayer (sam) on gold surface

Masato Tazaki
, Kenji Okada
, Kenshi Yakata
, Koji Nakano
, Masashi Sakai
, Tadashi Yonemitsu

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

High purity synthesis of ω-ferrocenylalkanethiols (Fc(CH₂)_n-SH, n=6, 8, 11) was developed for their use in self-assembled monolayers on gold surface. The method employs a separation and purification of isothiuronium salt 6 to improve the purity of final products 7. The use of hazardous mercury in the Clemmensen reduction of acylferrocene 4 to alkylferrocenes 5 is avoided by an alternative LAH/AlCl₃ reduction.

Original language	English
Pages (from-to)	239-249
Number of pages	11
Journal	Phosphorus, Sulfur and Silicon and Related Elements
Volume	167
DOIs	https://doi.org/10.1080/10426500008082402
Publication status	Published - 2000

All Science Journal Classification (ASJC) codes

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426500008082402

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abstract = "High purity synthesis of ω-ferrocenylalkanethiols (Fc(CH2)n-SH, n=6, 8, 11) was developed for their use in self-assembled monolayers on gold surface. The method employs a separation and purification of isothiuronium salt 6 to improve the purity of final products 7. The use of hazardous mercury in the Clemmensen reduction of acylferrocene 4 to alkylferrocenes 5 is avoided by an alternative LAH/AlCl3 reduction.",

author = "Masato Tazaki and Kenji Okada and Kenshi Yakata and Koji Nakano and Masashi Sakai and Tadashi Yonemitsu",

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AU - Tazaki, Masato

AU - Okada, Kenji

AU - Yakata, Kenshi

AU - Nakano, Koji

AU - Sakai, Masashi

AU - Yonemitsu, Tadashi

PY - 2000

Y1 - 2000

N2 - High purity synthesis of ω-ferrocenylalkanethiols (Fc(CH2)n-SH, n=6, 8, 11) was developed for their use in self-assembled monolayers on gold surface. The method employs a separation and purification of isothiuronium salt 6 to improve the purity of final products 7. The use of hazardous mercury in the Clemmensen reduction of acylferrocene 4 to alkylferrocenes 5 is avoided by an alternative LAH/AlCl3 reduction.

AB - High purity synthesis of ω-ferrocenylalkanethiols (Fc(CH2)n-SH, n=6, 8, 11) was developed for their use in self-assembled monolayers on gold surface. The method employs a separation and purification of isothiuronium salt 6 to improve the purity of final products 7. The use of hazardous mercury in the Clemmensen reduction of acylferrocene 4 to alkylferrocenes 5 is avoided by an alternative LAH/AlCl3 reduction.

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UR - https://www.scopus.com/pages/publications/0034355361#tab=citedBy

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JO - Phosphorus, Sulfur and Silicon and Related Elements

JF - Phosphorus, Sulfur and Silicon and Related Elements

ER -

Facile, convenient synthesis of highly pure ω-ferrocenylalkanethiols as probes for self-assembled monolayer (sam) on gold surface

Abstract

All Science Journal Classification (ASJC) codes

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