Extraction of electrons from H2 with a NiIRu I catalyst

Takahiro Matsumoto; Bunsho Kure; Seiji Ogo

doi:10.1246/cl.2008.970

Extraction of electrons from H₂ with a Ni^IRu ^I catalyst

Takahiro Matsumoto, Bunsho Kure, Seiji Ogo

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The mechanism of extraction of electrons from H₂ catalyzed by hydrogenases has proven challenging to elucidate. Catalytic extraction of electrons from H₂ has been achieved by use of a low-valent Ni ^IRu^I complex [Ni^I(μ-SR)₂Ru ^I(η⁶-C₆Me₆)]{μ-SR) ₂ = N,N′-dimethyl-N,N′-bis(2-mercaptoethyl)-1,3- propanediamine) as the active catalyst with evolution of H₂ under ambient conditions. The electrons extracted from H₂ have been used for a catalytic reduction of Cu²⁺ to Cu⁰ with the NiRu complexes.

Original language	English
Pages (from-to)	970-971
Number of pages	2
Journal	Chemistry Letters
Volume	37
Issue number	9
DOIs	https://doi.org/10.1246/cl.2008.970
Publication status	Published - Sept 5 2008

All Science Journal Classification (ASJC) codes

Chemistry(all)

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abstract = "The mechanism of extraction of electrons from H2 catalyzed by hydrogenases has proven challenging to elucidate. Catalytic extraction of electrons from H2 has been achieved by use of a low-valent Ni IRuI complex [NiI(μ-SR)2Ru I(η6-C6Me6)]{μ-SR) 2 = N,N′-dimethyl-N,N′-bis(2-mercaptoethyl)-1,3- propanediamine) as the active catalyst with evolution of H2 under ambient conditions. The electrons extracted from H2 have been used for a catalytic reduction of Cu2+ to Cu0 with the NiRu complexes.",

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AU - Ogo, Seiji

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AB - The mechanism of extraction of electrons from H2 catalyzed by hydrogenases has proven challenging to elucidate. Catalytic extraction of electrons from H2 has been achieved by use of a low-valent Ni IRuI complex [NiI(μ-SR)2Ru I(η6-C6Me6)]{μ-SR) 2 = N,N′-dimethyl-N,N′-bis(2-mercaptoethyl)-1,3- propanediamine) as the active catalyst with evolution of H2 under ambient conditions. The electrons extracted from H2 have been used for a catalytic reduction of Cu2+ to Cu0 with the NiRu complexes.

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Extraction of electrons from H₂ with a Ni^IRu ^I catalyst

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