Experimental study of reductive elimination of H 2 from rhodium hydride species

Daisuke Inoki; Takahiro Matsumoto; Hidetaka Nakai; Seiji Ogo

doi:10.1021/om2009759

Experimental study of reductive elimination of H ₂ from rhodium hydride species

Daisuke Inoki, Takahiro Matsumoto, Hidetaka Nakai, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

A Rh ^III monohydride terpyridine complex undergoes reductive elimination of H ₂ in CH ₃CN to form a dinuclear Rh ^II complex with a metal-metal bond. Kinetic studies have revealed that the conversion from the monohydride species to the dinuclear species with evolution of H ₂ obeys first-order kinetics and have determined the kinetic deuterium isotope effect value to be 2.0. We discuss the mechanism for the reductive elimination of H ₂ from rhodium hydride species.

Original language	English
Pages (from-to)	2996-3001
Number of pages	6
Journal	Organometallics
Volume	31
Issue number	8
DOIs	https://doi.org/10.1021/om2009759
Publication status	Published - Apr 23 2012

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om2009759

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abstract = "A Rh III monohydride terpyridine complex undergoes reductive elimination of H 2 in CH 3CN to form a dinuclear Rh II complex with a metal-metal bond. Kinetic studies have revealed that the conversion from the monohydride species to the dinuclear species with evolution of H 2 obeys first-order kinetics and have determined the kinetic deuterium isotope effect value to be 2.0. We discuss the mechanism for the reductive elimination of H 2 from rhodium hydride species.",

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AU - Nakai, Hidetaka

AU - Ogo, Seiji

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AB - A Rh III monohydride terpyridine complex undergoes reductive elimination of H 2 in CH 3CN to form a dinuclear Rh II complex with a metal-metal bond. Kinetic studies have revealed that the conversion from the monohydride species to the dinuclear species with evolution of H 2 obeys first-order kinetics and have determined the kinetic deuterium isotope effect value to be 2.0. We discuss the mechanism for the reductive elimination of H 2 from rhodium hydride species.

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Experimental study of reductive elimination of H ₂ from rhodium hydride species

Abstract

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