Expanding the synthesizable multisubstituted benzo[b] thiophenes via 6,7-thienobenzynes generated from o -silylaryl triflate-type precursors

Suguru Yoshida, Tomoko Kuribara, Takamoto Morita, Tsubasa Matsuzawa, Kazushi Morimoto, Takuya Kobayashi, Takamitsu Hosoya

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

Various 2,3-disubstituted 6,7-thienobenzynes have been efficiently generated from the corresponding o-silylaryl triflate-type precursors by activation with fluoride ions. The method has expanded the scope of synthesizable multisubstituted benzothiophenes, including those with various heteroatom substituents, and can be applied to the synthesis of EP4 antagonist analogs.

Original languageEnglish
Pages (from-to)21754-21758
Number of pages5
JournalRSC Advances
Volume8
Issue number39
DOIs
Publication statusPublished - 2018
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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