Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [FeIII(qnal) 2][Pd(dmit)2]5·acetone

Kazuyuki Takahashi; Heng Bo Cui; Yoshinori Okano; Hayao Kobayashi; Hatsumi Mori; Hiroyuki Tajima; Yasuaki Einaga; Osamu Sato

doi:10.1021/ja801585r

Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [Fe^III(qnal) ₂][Pd(dmit)₂]₅·acetone

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Hatsumi Mori, Hiroyuki Tajima, Yasuaki Einaga, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

150 Citations (Scopus)

Abstract

A novel spin-crossover molecular conductor, [Fe(qnal)₂][Pd(dmit)₂]₅·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)₂ cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)₂ layer.

Original language	English
Pages (from-to)	6688-6689
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	21
DOIs	https://doi.org/10.1021/ja801585r
Publication status	Published - May 28 2008

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja801585r

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Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [Fe^III(qnal) ₂][Pd(dmit)₂]₅·acetone. / Takahashi, Kazuyuki; Cui, Heng Bo; Okano, Yoshinori et al.
In: Journal of the American Chemical Society, Vol. 130, No. 21, 28.05.2008, p. 6688-6689.

Research output: Contribution to journal › Article › peer-review

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abstract = "A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.",

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AU - Kobayashi, Hayao

AU - Mori, Hatsumi

AU - Tajima, Hiroyuki

AU - Einaga, Yasuaki

AU - Sato, Osamu

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Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [Fe^III(qnal) ₂][Pd(dmit)₂]₅·acetone

Abstract

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