Evidence for Pt(II)-based molecular catalysis in the thermal reduction of water into molecular hydrogen

Kosei Yamauchi; Shigeyuki Masaoka; Ken Sakai

doi:10.1021/ja902245e

Evidence for Pt(II)-based molecular catalysis in the thermal reduction of water into molecular hydrogen

Kosei Yamauchi, Shigeyuki Masaoka, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

(Figure Presented) The one-electron-reduced form of methylviologen (MV ^+.), generated in situ by bulk electrolysis of methylviologen (MV²⁺), was for the first time reacted with various Pt(II) complexes in aqueous media without light irradiation to reveal that thermal reduction of water into molecular hydrogen is indeed highly promoted by the Pt(II)-based molecular catalysts.

Original language	English
Pages (from-to)	8404-8406
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	131
Issue number	24
DOIs	https://doi.org/10.1021/ja902245e
Publication status	Published - Jun 24 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)
Biochemistry
Catalysis
Colloid and Surface Chemistry

Access to Document

10.1021/ja902245e

Cite this

@article{14c336c445804d42b05a4c761e111bd4,

title = "Evidence for Pt(II)-based molecular catalysis in the thermal reduction of water into molecular hydrogen",

abstract = "(Figure Presented) The one-electron-reduced form of methylviologen (MV +.), generated in situ by bulk electrolysis of methylviologen (MV2+), was for the first time reacted with various Pt(II) complexes in aqueous media without light irradiation to reveal that thermal reduction of water into molecular hydrogen is indeed highly promoted by the Pt(II)-based molecular catalysts.",

author = "Kosei Yamauchi and Shigeyuki Masaoka and Ken Sakai",

year = "2009",

month = jun,

day = "24",

doi = "10.1021/ja902245e",

language = "English",

volume = "131",

pages = "8404--8406",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "24",

}

TY - JOUR

T1 - Evidence for Pt(II)-based molecular catalysis in the thermal reduction of water into molecular hydrogen

AU - Yamauchi, Kosei

AU - Masaoka, Shigeyuki

AU - Sakai, Ken

PY - 2009/6/24

Y1 - 2009/6/24

N2 - (Figure Presented) The one-electron-reduced form of methylviologen (MV +.), generated in situ by bulk electrolysis of methylviologen (MV2+), was for the first time reacted with various Pt(II) complexes in aqueous media without light irradiation to reveal that thermal reduction of water into molecular hydrogen is indeed highly promoted by the Pt(II)-based molecular catalysts.

AB - (Figure Presented) The one-electron-reduced form of methylviologen (MV +.), generated in situ by bulk electrolysis of methylviologen (MV2+), was for the first time reacted with various Pt(II) complexes in aqueous media without light irradiation to reveal that thermal reduction of water into molecular hydrogen is indeed highly promoted by the Pt(II)-based molecular catalysts.

UR - http://www.scopus.com/inward/record.url?scp=67650537056&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67650537056&partnerID=8YFLogxK

U2 - 10.1021/ja902245e

DO - 10.1021/ja902245e

M3 - Article

C2 - 19462999

AN - SCOPUS:67650537056

SN - 0002-7863

VL - 131

SP - 8404

EP - 8406

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 24

ER -

Evidence for Pt(II)-based molecular catalysis in the thermal reduction of water into molecular hydrogen

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this