TY - JOUR
T1 - Enhancing viscoelastic and mechanical performances of natural rubber through variation of large and small rubber particle combinations
AU - Sriring, Manus
AU - Nimpaiboon, Adun
AU - Kumarn, Sirirat
AU - Takahara, Atsushi
AU - Sakdapipanich, Jitladda
N1 - Funding Information:
The authors would like to acknowledge the financial support from the Center of Excellence for Innovation in Chemistry (PERCH-CIC) , Commission on Higher Education, Ministry of Education, Thailand and the Science Achievement Scholarship of Thailand (SAST), Thailand . Sincere appreciation is extended to the Thai Rubber Latex Group Public Company Limited for their kind support of the NR latex.
Publisher Copyright:
© 2019 Elsevier Ltd
PY - 2020/1
Y1 - 2020/1
N2 - There have been several reports investigating independent properties of large- (LRP) and small rubber particles (SRP). This work envisaged that, when co-existing, they could offer exceptional viscoelastic and mechanical properties from both components. Latex samples of various mixing ratios were prepared and properties of their rubber films were investigated against those of pure LRP and SRP to find that those containing 10–30% SRP were the best in mechanical strength and elasticity. This could be due to the combination of stronger phospholipid linkages in the LRP and void-filling ability of the SRP. The presence of SRP was shown to enhance curability in the vulcanised samples resulting in better mechanical performance of the vulcanisates. The 70/30 (LRP/SRP) blend showed the best thermal aging resistance among the vulcanisates. This suggested that the mixing ratios of the LRP and SRP contents were tunable to improve desirable properties of rubber products of interest, both green and cured.
AB - There have been several reports investigating independent properties of large- (LRP) and small rubber particles (SRP). This work envisaged that, when co-existing, they could offer exceptional viscoelastic and mechanical properties from both components. Latex samples of various mixing ratios were prepared and properties of their rubber films were investigated against those of pure LRP and SRP to find that those containing 10–30% SRP were the best in mechanical strength and elasticity. This could be due to the combination of stronger phospholipid linkages in the LRP and void-filling ability of the SRP. The presence of SRP was shown to enhance curability in the vulcanised samples resulting in better mechanical performance of the vulcanisates. The 70/30 (LRP/SRP) blend showed the best thermal aging resistance among the vulcanisates. This suggested that the mixing ratios of the LRP and SRP contents were tunable to improve desirable properties of rubber products of interest, both green and cured.
UR - http://www.scopus.com/inward/record.url?scp=85075797473&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85075797473&partnerID=8YFLogxK
U2 - 10.1016/j.polymertesting.2019.106225
DO - 10.1016/j.polymertesting.2019.106225
M3 - Article
AN - SCOPUS:85075797473
SN - 0142-9418
VL - 81
JO - Polymer Testing
JF - Polymer Testing
M1 - 106225
ER -