Enhanced and Optically Switchable Proton Conductivity in a Melting Coordination Polymer Crystal

Sanjog S. Nagarkar, Satoshi Horike, Tomoya Itakura, Benjamin Le Ouay, Aude Demessence, Masahiko Tsujimoto, Susumu Kitagawa

Research output: Contribution to journalArticlepeer-review

73 Citations (Scopus)


The melting behavior of a coordination polymer (CP) crystal was utilized to achieve enhanced and optically switchable proton conductivity in the solid state. The strong acid molecules (triflic acid) were doped in one-dimensional (1D) CP, [Zn(HPO4)(H2PO4)2](ImH2)2 (ImH2=monoprotonated imidazole) in the melt state, and overall enhancement in the proton conductivity was obtained. The enhanced proton conductivity is assigned to increased number of mobile protons and defects created by acid doping. Optical control over proton conductivity in the CP is achieved by doping of the photo acid molecule pyranine into the melted CP. The pyranine reversibly generates the mobile acidic protons and local defects in the glassy state of CP resulting in the bulk switchable conductivity mediated by light irradiation. Utilization of CP crystal in liquid state enables to be a novel route to incorporate functional molecules and defects, and it provides a tool to control the bulk properties of the CP material.

Original languageEnglish
Pages (from-to)4976-4981
Number of pages6
JournalAngewandte Chemie - International Edition
Issue number18
Publication statusPublished - Apr 24 2017
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)


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