Enantioselective Epoxidation of 2,2-Dimethylchromenes Using Achiral Mn-Salen Complex as a Catalyst in the Presence of Chiral Amine

Takashi Hashihayata; Yoshio Ito; Tsutomu Katsuki

doi:10.1055/s-1996-5695

Enantioselective Epoxidation of 2,2-Dimethylchromenes Using Achiral Mn-Salen Complex as a Catalyst in the Presence of Chiral Amine

Takashi Hashihayata, Yoshio Ito, Tsutomu Katsuki

Organic and Biological Chemistry

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

Epoxidation of 2,2-dimethylchromene derivatives using achiral (salen)manganese(III) complexes as catalysts in the presence of (-)-sparteine was found to proceed enantioselectively (up to 73% ee).

Original language	English
Pages (from-to)	1079-1081
Number of pages	3
Journal	Synlett
Volume	1996
Issue number	11
DOIs	https://doi.org/10.1055/s-1996-5695
Publication status	Published - 1996

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Organic Chemistry

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10.1055/s-1996-5695

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@article{240f0c1b03714878a37433bee155d8f5,

title = "Enantioselective Epoxidation of 2,2-Dimethylchromenes Using Achiral Mn-Salen Complex as a Catalyst in the Presence of Chiral Amine",

abstract = "Epoxidation of 2,2-dimethylchromene derivatives using achiral (salen)manganese(III) complexes as catalysts in the presence of (-)-sparteine was found to proceed enantioselectively (up to 73% ee).",

author = "Takashi Hashihayata and Yoshio Ito and Tsutomu Katsuki",

year = "1996",

doi = "10.1055/s-1996-5695",

language = "English",

volume = "1996",

pages = "1079--1081",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "11",

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T1 - Enantioselective Epoxidation of 2,2-Dimethylchromenes Using Achiral Mn-Salen Complex as a Catalyst in the Presence of Chiral Amine

AU - Hashihayata, Takashi

AU - Ito, Yoshio

AU - Katsuki, Tsutomu

PY - 1996

Y1 - 1996

N2 - Epoxidation of 2,2-dimethylchromene derivatives using achiral (salen)manganese(III) complexes as catalysts in the presence of (-)-sparteine was found to proceed enantioselectively (up to 73% ee).

AB - Epoxidation of 2,2-dimethylchromene derivatives using achiral (salen)manganese(III) complexes as catalysts in the presence of (-)-sparteine was found to proceed enantioselectively (up to 73% ee).

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U2 - 10.1055/s-1996-5695

DO - 10.1055/s-1996-5695

M3 - Article

AN - SCOPUS:0000899387

SN - 0936-5214

VL - 1996

SP - 1079

EP - 1081

JO - Synlett

JF - Synlett

IS - 11

ER -

Enantioselective Epoxidation of 2,2-Dimethylchromenes Using Achiral Mn-Salen Complex as a Catalyst in the Presence of Chiral Amine

Abstract

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