Enantiocontrolled synthesis of (+)-curcuquinone and (-)-curcuhydroquinone

Tomoyuki Yoshimura; Hidetoshi Kisyuku; Tomoyo Kamei; Kenya Takabatake; Mitsuru Shindo; Kozo Shishido

Enantiocontrolled synthesis of (+)-curcuquinone and (-)-curcuhydroquinone

Tomoyuki Yoshimura, Hidetoshi Kisyuku, Tomoyo Kamei, Kenya Takabatake, Mitsuru Shindo, Kozo Shishido

Research output: Contribution to journal › Article › peer-review

Abstract

An enantiocontrolled synthesis of the monocyclic bisabolene-type sesquiterpenoids (+)-curcuquinone 1 and (-)-curcuhydroquinone 2 has been accomplished using a porcine pancreatic lipase (PPL)-mediated desymmetrization of the prochiral σ-symmetrical 2-aryl-1,3-propanediol 6 as the key reaction step.

Original language	English
Pages (from-to)	247-255
Number of pages	9
Journal	Arkivoc
Volume	2003
Issue number	8
Publication status	Published - 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

Cite this

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abstract = "An enantiocontrolled synthesis of the monocyclic bisabolene-type sesquiterpenoids (+)-curcuquinone 1 and (-)-curcuhydroquinone 2 has been accomplished using a porcine pancreatic lipase (PPL)-mediated desymmetrization of the prochiral σ-symmetrical 2-aryl-1,3-propanediol 6 as the key reaction step.",

author = "Tomoyuki Yoshimura and Hidetoshi Kisyuku and Tomoyo Kamei and Kenya Takabatake and Mitsuru Shindo and Kozo Shishido",

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AU - Yoshimura, Tomoyuki

AU - Kisyuku, Hidetoshi

AU - Kamei, Tomoyo

AU - Takabatake, Kenya

AU - Shindo, Mitsuru

AU - Shishido, Kozo

PY - 2003

Y1 - 2003

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AB - An enantiocontrolled synthesis of the monocyclic bisabolene-type sesquiterpenoids (+)-curcuquinone 1 and (-)-curcuhydroquinone 2 has been accomplished using a porcine pancreatic lipase (PPL)-mediated desymmetrization of the prochiral σ-symmetrical 2-aryl-1,3-propanediol 6 as the key reaction step.

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Enantiocontrolled synthesis of (+)-curcuquinone and (-)-curcuhydroquinone

Abstract

All Science Journal Classification (ASJC) codes

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