TY - JOUR
T1 - Electrooxidative copolymerization of 3,4-Ethylenedioxithiophene and benzene from a mixture of each monomer
AU - Tanaka, Eisaku
AU - Tateno, Hiroyuki
AU - Matsumura, Yoshimasa
AU - Nakabayashi, Koji
AU - Kawamura, Izuru
AU - Atobe, Mahito
N1 - Funding Information:
This work was supported by Grants-in-Aid for Scientific Research (Nos. JP15K13691, JP15H05847 and JP15H03843) from the Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT).
Publisher Copyright:
© 2018 The Chemical Society of Japan.
PY - 2018
Y1 - 2018
N2 - Electrooxidative copolymerization of 3,4-ethylenedioxithiophene (EDOT) and benzene from a mixture of the monomers with concentrations of 5mM EDOT and 5M benzene produced copolymer films on an anode surface. The formation of copolymer films and characterization of their electrochemical properties was confirmed using Fourier transform infrared (FTIR) spectroscopy, ultravioletvisible absorption (UVvis) spectroscopy, energy dispersive X-ray (EDX) spectroscopy, cyclic voltammetry (CV), and solid-state carbon-13 nuclear magnetic resonance (13CNMR) spectroscopy measurements. Furthermore, the copolymerization ratio could be controlled by selection of the oxidation potential applied for copolymerization.
AB - Electrooxidative copolymerization of 3,4-ethylenedioxithiophene (EDOT) and benzene from a mixture of the monomers with concentrations of 5mM EDOT and 5M benzene produced copolymer films on an anode surface. The formation of copolymer films and characterization of their electrochemical properties was confirmed using Fourier transform infrared (FTIR) spectroscopy, ultravioletvisible absorption (UVvis) spectroscopy, energy dispersive X-ray (EDX) spectroscopy, cyclic voltammetry (CV), and solid-state carbon-13 nuclear magnetic resonance (13CNMR) spectroscopy measurements. Furthermore, the copolymerization ratio could be controlled by selection of the oxidation potential applied for copolymerization.
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U2 - 10.1246/bcsj.20170319
DO - 10.1246/bcsj.20170319
M3 - Article
AN - SCOPUS:85042134774
SN - 0009-2673
VL - 91
SP - 141
EP - 146
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 2
ER -