The electronic and geometric structures of some novel donor-acceptor polymers containing alternating electron donating group X (X=CH2, SiH2, S, O or NH) and electron accepting group Y (Y=>C=CH2, >C=O, >C=CF2 or >C=C(CN)2) along the conjugated cis-polyacetylene backbone, obtained on the basis of the one-dimensional tight-binding self-consistent field-crystal orbital (SCF-CO) method at the MNDO-AM1 level of approximation, are presented.
All Science Journal Classification (ASJC) codes
- Condensed Matter Physics
- Organic Chemistry
- Polymers and Plastics
- Materials Chemistry