Electrodeposition of metallic molybdenum films in molten ZnCl2-NaCl-KCl-MoCl5 systems at 250°C

Hironori Nakajima; Toshiyuki Nohira; Rika Hagiwara; Koji Nitta; Shinji Inazawa; Kazunori Okada

Electrodeposition of metallic molybdenum films in molten ZnCl₂-NaCl-KCl-MoCl₅ systems at 250°C

Hironori Nakajima, Toshiyuki Nohira, Rika Hagiwara, Koji Nitta, Shinji Inazawa, Kazunori Okada

Research output: Contribution to journal › Article › peer-review

Abstract

Metallic molybdenum film was electrodeposited in ZnCl₂-NaCl-KCl (0.60:0.20:0.20, in mole fraction) melt containing MoCl₅ at 250°C. In this melt, a dense film was obtained by potentiostatic electrolysis at 0.15 V vs Zn(II)/Zn for 3 h. Addition of 4% (mole fraction) of KF to the melt led to larger cathodic current in cyclic voltammogram, and gave a dense, more adhesive and smooth metal film with a thickness of ca. 0.5 μm.

Original language	English
Pages (from-to)	16-20
Number of pages	5
Journal	Journal of Rare Earths
Volume	23
Issue number	SUPPL. 1
Publication status	Published - Oct 2005
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Geochemistry and Petrology

Cite this

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title = "Electrodeposition of metallic molybdenum films in molten ZnCl2-NaCl-KCl-MoCl5 systems at 250°C",

abstract = "Metallic molybdenum film was electrodeposited in ZnCl2-NaCl-KCl (0.60:0.20:0.20, in mole fraction) melt containing MoCl5 at 250°C. In this melt, a dense film was obtained by potentiostatic electrolysis at 0.15 V vs Zn(II)/Zn for 3 h. Addition of 4% (mole fraction) of KF to the melt led to larger cathodic current in cyclic voltammogram, and gave a dense, more adhesive and smooth metal film with a thickness of ca. 0.5 μm.",

author = "Hironori Nakajima and Toshiyuki Nohira and Rika Hagiwara and Koji Nitta and Shinji Inazawa and Kazunori Okada",

year = "2005",

month = oct,

language = "English",

volume = "23",

pages = "16--20",

journal = "Journal of Rare Earths",

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T1 - Electrodeposition of metallic molybdenum films in molten ZnCl2-NaCl-KCl-MoCl5 systems at 250°C

AU - Nakajima, Hironori

AU - Nohira, Toshiyuki

AU - Hagiwara, Rika

AU - Nitta, Koji

AU - Inazawa, Shinji

AU - Okada, Kazunori

PY - 2005/10

Y1 - 2005/10

N2 - Metallic molybdenum film was electrodeposited in ZnCl2-NaCl-KCl (0.60:0.20:0.20, in mole fraction) melt containing MoCl5 at 250°C. In this melt, a dense film was obtained by potentiostatic electrolysis at 0.15 V vs Zn(II)/Zn for 3 h. Addition of 4% (mole fraction) of KF to the melt led to larger cathodic current in cyclic voltammogram, and gave a dense, more adhesive and smooth metal film with a thickness of ca. 0.5 μm.

AB - Metallic molybdenum film was electrodeposited in ZnCl2-NaCl-KCl (0.60:0.20:0.20, in mole fraction) melt containing MoCl5 at 250°C. In this melt, a dense film was obtained by potentiostatic electrolysis at 0.15 V vs Zn(II)/Zn for 3 h. Addition of 4% (mole fraction) of KF to the melt led to larger cathodic current in cyclic voltammogram, and gave a dense, more adhesive and smooth metal film with a thickness of ca. 0.5 μm.

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JO - Journal of Rare Earths

JF - Journal of Rare Earths

IS - SUPPL. 1

ER -

Electrodeposition of metallic molybdenum films in molten ZnCl₂-NaCl-KCl-MoCl₅ systems at 250°C

Abstract

All Science Journal Classification (ASJC) codes

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