Electrochemical methyl-transfer reaction to alkylthiol catalyzed by hydrophobic vitamin B 12

Ling Pan; Hisashi Shimakoshi; Yoshio Hisaeda

doi:10.1246/cl.2009.26

Electrochemical methyl-transfer reaction to alkylthiol catalyzed by hydrophobic vitamin B ₁₂

Ling Pan, Hisashi Shimakoshi, Yoshio Hisaeda

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6 Citations (Scopus)

Abstract

The catalytic methyl-transfer reaction from methyl tosylate to 1-octanethiol was carried out in the presence of heptamethyl cobyrinate perchlorate, hydrophobic vitamin B ₁₂, under electrochemical conditions at -1.0 V vs. Ag/AgCl using a carbon-felt cathode and a zinc plate anode as the sacrificial electrode in an undivided cell. This catalytic reaction proceeded via the formation and dissociation of the cobalt-carbon bond in the hydrophobic vitamin B ₁₂.

Original language	English
Pages (from-to)	26-27
Number of pages	2
Journal	Chemistry Letters
Volume	38
Issue number	1
DOIs	https://doi.org/10.1246/cl.2009.26
Publication status	Published - 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2009.26

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title = "Electrochemical methyl-transfer reaction to alkylthiol catalyzed by hydrophobic vitamin B 12 ",

abstract = "The catalytic methyl-transfer reaction from methyl tosylate to 1-octanethiol was carried out in the presence of heptamethyl cobyrinate perchlorate, hydrophobic vitamin B 12, under electrochemical conditions at -1.0 V vs. Ag/AgCl using a carbon-felt cathode and a zinc plate anode as the sacrificial electrode in an undivided cell. This catalytic reaction proceeded via the formation and dissociation of the cobalt-carbon bond in the hydrophobic vitamin B 12.",

author = "Ling Pan and Hisashi Shimakoshi and Yoshio Hisaeda",

year = "2009",

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T1 - Electrochemical methyl-transfer reaction to alkylthiol catalyzed by hydrophobic vitamin B 12

AU - Pan, Ling

AU - Shimakoshi, Hisashi

AU - Hisaeda, Yoshio

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AB - The catalytic methyl-transfer reaction from methyl tosylate to 1-octanethiol was carried out in the presence of heptamethyl cobyrinate perchlorate, hydrophobic vitamin B 12, under electrochemical conditions at -1.0 V vs. Ag/AgCl using a carbon-felt cathode and a zinc plate anode as the sacrificial electrode in an undivided cell. This catalytic reaction proceeded via the formation and dissociation of the cobalt-carbon bond in the hydrophobic vitamin B 12.

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JO - Chemistry Letters

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IS - 1

ER -

Electrochemical methyl-transfer reaction to alkylthiol catalyzed by hydrophobic vitamin B ₁₂

Abstract

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