Efficient deep-blue organic light-emitting diodes based on 9,9-Bis(4-biphenylyl)fluorene derivatives

Naoki Matsumoto, Takanori Miyazaki, Masakazu Nishiyama, Chihaya Adachi

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50 Citations (Scopus)


We fabricated highly efficient deep-blue organic light-emitting diodes (OLEDs) composed of 2,7-bis(4'-diphenylamino-1,1'-biphenyl-4-yl)-9,9-bis(1,1'- biphenyl-4-yl)-9H-fluorene (FLBD) as an emitter doped into a wider energy gap host of 2,7-bis(1,1'-biphenyl-4-yl)-9,9-bis(1,1'-biphenyl-4-yl)-9H-fluorene (FLBH). We investigated the dominant factors for external electroluminescence quantum efficiency (ηext) in the deep-blue OLEDs by focusing on the carrier balance in the emitting layer (EML), the location and width of the carrier recombination zone, and carrier-induced exciton quenching. The ηext value of the OLEDs strongly depended on the hole injection efficiency from a hole transport layer (HTL) to the EML. By controlling the hole injection barrier into the EML and balancing the number of electrons and holes in the EML using HTLs having various highest occupied molecular orbital levels, we obtained the highest ηext of 5.4% with deep-blue Commission International De L'Eclairage coordinates of x = 0.15 and y = 0.09. Additionally, we found that the width of the carrier recombination zone tightly correlates to the hole injection efficiency into the EML.

Original languageEnglish
Pages (from-to)6261-6266
Number of pages6
JournalJournal of Physical Chemistry C
Issue number15
Publication statusPublished - Apr 16 2009

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films


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