TY - JOUR
T1 - Effect of the pre-treated pyrolysis fuel oil
T2 - Coal tar pitch ratio on the spinnability and oxidation properties of isotropic pitch precursors and the mechanical properties of derived carbon fibers
AU - Liu, Jinchang
AU - Shimanoe, Hiroki
AU - Choi, Jong Eun
AU - Ko, Seunghyun
AU - Jeon, Young Pyo
AU - Nakabayashi, Koji
AU - Miyawaki, Jin
AU - Yoon, Seong Ho
N1 - Funding Information:
This work was supported by the Technology Innovation Program [10082582, Development of petroleum-based high quality mesophase pitch and high yield mesophase pitch for premium carbon mate-rials] funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea).
Funding Information:
Acknowledgements This work was supported by the Technology Innovation Program [10082582, Development of petroleum-based high quality mesophase pitch and high yield mesophase pitch for premium carbon materials] funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea).
PY - 2019/4
Y1 - 2019/4
N2 - Pitch precursors affording excellent spinnability, high-level oxidation-resistance, and good carbonization yields were prepared by bromination–dehydrobromination of various ratios of pyrolyzed fuel oil and coal tar pitch. The pitches exhibited spin-nabilities that were much better than those of pitches prepared via simple distillation. A pitch prepared using a 1:2 ratio of fuel oil and coal tar pitch exhibited the best tensile strength. Pitch fibers of diameter 8.9 ± 0.1 μm were stabilized at 270 °C without soaking time after heating at a rate of 0.5 °C/min and carbonized at 1100 °C for 1 h after heating at 5 °C/min. The resulting carbon fibers exhibited a tensile strength, elongation, Young’s modulus, and average diameter of 1700 ± 170 MPa, 1.6 ± 0.1%, 106 ± 37 GPa, and 7.1 ± 0.2 μm, respectively.
AB - Pitch precursors affording excellent spinnability, high-level oxidation-resistance, and good carbonization yields were prepared by bromination–dehydrobromination of various ratios of pyrolyzed fuel oil and coal tar pitch. The pitches exhibited spin-nabilities that were much better than those of pitches prepared via simple distillation. A pitch prepared using a 1:2 ratio of fuel oil and coal tar pitch exhibited the best tensile strength. Pitch fibers of diameter 8.9 ± 0.1 μm were stabilized at 270 °C without soaking time after heating at a rate of 0.5 °C/min and carbonized at 1100 °C for 1 h after heating at 5 °C/min. The resulting carbon fibers exhibited a tensile strength, elongation, Young’s modulus, and average diameter of 1700 ± 170 MPa, 1.6 ± 0.1%, 106 ± 37 GPa, and 7.1 ± 0.2 μm, respectively.
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U2 - 10.1007/s42823-019-00020-4
DO - 10.1007/s42823-019-00020-4
M3 - Article
AN - SCOPUS:85065818923
SN - 1976-4251
VL - 29
SP - 193
EP - 202
JO - Carbon Letters
JF - Carbon Letters
IS - 2
ER -
