Effect of temperature on the interactions between low bandgap polymer and ionic liquids

Pankaj Attri; Seung Hyun Lee; Sun Woo Hwang; Joong Il Kim; Won Jang; Young Beom Kim; Jung Ho Park; Gi Chung Kwon; Eun Ha Choi; In Tae Kim

doi:10.1016/j.tca.2013.12.022

Effect of temperature on the interactions between low bandgap polymer and ionic liquids

Pankaj Attri, Seung Hyun Lee, Sun Woo Hwang, Joong Il Kim, Won Jang, Young Beom Kim, Jung Ho Park, Gi Chung Kwon, Eun Ha Choi, In Tae Kim

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Abstract In this paper, we have examined the effect of temperature on the interactions between imidazolium and ammonium based ionic liquids (ILs) and the low bandgap polymer (poly(2-heptadecyl-4-vinylthieno[3,4-d]thiazole) (PHVTT)). With the aim of exploring the utility of low bandgap polymers, we have carried out the interaction studies of the polymer with the ILs and investigated the behavior of polymer in the presence of ILs as the function of temperature. Recently, ILs have attracted extensive attention in polymer sciences. In this work, we have studied the temperature dependent interactions between the protic IL (1-methylimidazolium chloride ([Mim]Cl) from imidazolium family) and aprotic ILs (tributylmethylammonium methyl sulfate ([N₁₄₄₄][MeSO ₄]) from ammonium family and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) from imidazolium family) with a low bandgap polymer. Our experimental data of UV-vis spectroscopy, photoluminescence (PL) spectroscopy, FT-IR spectroscopy, density (ρ) and speed of sound (u) as a function of temperature from 25 to 40 C with the interval of 5 C, clearly reveal that even at high temperature, [Bmim]Cl interacts strongly with the polymer as compared to other studied ILs.

Original language	English
Pages (from-to)	15-21
Number of pages	7
Journal	Thermochimica Acta
Volume	579
DOIs	https://doi.org/10.1016/j.tca.2013.12.022
Publication status	Published - Mar 10 2014
Externally published	Yes

All Science Journal Classification (ASJC) codes

Instrumentation
Condensed Matter Physics
Physical and Theoretical Chemistry

Access to Document

10.1016/j.tca.2013.12.022

Cite this

@article{6be340e5d91945118b9c9cc911be8ea4,

title = "Effect of temperature on the interactions between low bandgap polymer and ionic liquids",

abstract = "Abstract In this paper, we have examined the effect of temperature on the interactions between imidazolium and ammonium based ionic liquids (ILs) and the low bandgap polymer (poly(2-heptadecyl-4-vinylthieno[3,4-d]thiazole) (PHVTT)). With the aim of exploring the utility of low bandgap polymers, we have carried out the interaction studies of the polymer with the ILs and investigated the behavior of polymer in the presence of ILs as the function of temperature. Recently, ILs have attracted extensive attention in polymer sciences. In this work, we have studied the temperature dependent interactions between the protic IL (1-methylimidazolium chloride ([Mim]Cl) from imidazolium family) and aprotic ILs (tributylmethylammonium methyl sulfate ([N1444][MeSO 4]) from ammonium family and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) from imidazolium family) with a low bandgap polymer. Our experimental data of UV-vis spectroscopy, photoluminescence (PL) spectroscopy, FT-IR spectroscopy, density (ρ) and speed of sound (u) as a function of temperature from 25 to 40 C with the interval of 5 C, clearly reveal that even at high temperature, [Bmim]Cl interacts strongly with the polymer as compared to other studied ILs.",

author = "Pankaj Attri and Lee, {Seung Hyun} and Hwang, {Sun Woo} and Kim, {Joong Il} and Won Jang and Kim, {Young Beom} and Park, {Jung Ho} and Kwon, {Gi Chung} and Choi, {Eun Ha} and Kim, {In Tae}",

note = "Funding Information: We gratefully acknowledge SRC program of National Research Foundation of Korea (NRF) Grant funded by the Korean Government (MEST) (No. 20100029418 ). This work was supported by the New & Renewable Energy of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Knowledge Economy (No. 96002011003 ) and by Ministry of Knowledge Economy (MKE) , Korea as a project, “Full color 360 degree 3D holographic video making technology” and by Ministry of Culture, Sports and Tourism (MCST) and Korea Creative Contents Agency (KOCCA) in the Culture Technology Research & Development Program 2012 and in part by Kwangwoon University research fund 2013. ",

year = "2014",

month = mar,

day = "10",

doi = "10.1016/j.tca.2013.12.022",

language = "English",

volume = "579",

pages = "15--21",

journal = "Thermochimica Acta",

issn = "0040-6031",

publisher = "Elsevier",

}

TY - JOUR

T1 - Effect of temperature on the interactions between low bandgap polymer and ionic liquids

AU - Attri, Pankaj

AU - Lee, Seung Hyun

AU - Hwang, Sun Woo

AU - Kim, Joong Il

AU - Jang, Won

AU - Kim, Young Beom

AU - Park, Jung Ho

AU - Kwon, Gi Chung

AU - Choi, Eun Ha

AU - Kim, In Tae

N1 - Funding Information: We gratefully acknowledge SRC program of National Research Foundation of Korea (NRF) Grant funded by the Korean Government (MEST) (No. 20100029418 ). This work was supported by the New & Renewable Energy of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Knowledge Economy (No. 96002011003 ) and by Ministry of Knowledge Economy (MKE) , Korea as a project, “Full color 360 degree 3D holographic video making technology” and by Ministry of Culture, Sports and Tourism (MCST) and Korea Creative Contents Agency (KOCCA) in the Culture Technology Research & Development Program 2012 and in part by Kwangwoon University research fund 2013.

PY - 2014/3/10

Y1 - 2014/3/10

N2 - Abstract In this paper, we have examined the effect of temperature on the interactions between imidazolium and ammonium based ionic liquids (ILs) and the low bandgap polymer (poly(2-heptadecyl-4-vinylthieno[3,4-d]thiazole) (PHVTT)). With the aim of exploring the utility of low bandgap polymers, we have carried out the interaction studies of the polymer with the ILs and investigated the behavior of polymer in the presence of ILs as the function of temperature. Recently, ILs have attracted extensive attention in polymer sciences. In this work, we have studied the temperature dependent interactions between the protic IL (1-methylimidazolium chloride ([Mim]Cl) from imidazolium family) and aprotic ILs (tributylmethylammonium methyl sulfate ([N1444][MeSO 4]) from ammonium family and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) from imidazolium family) with a low bandgap polymer. Our experimental data of UV-vis spectroscopy, photoluminescence (PL) spectroscopy, FT-IR spectroscopy, density (ρ) and speed of sound (u) as a function of temperature from 25 to 40 C with the interval of 5 C, clearly reveal that even at high temperature, [Bmim]Cl interacts strongly with the polymer as compared to other studied ILs.

AB - Abstract In this paper, we have examined the effect of temperature on the interactions between imidazolium and ammonium based ionic liquids (ILs) and the low bandgap polymer (poly(2-heptadecyl-4-vinylthieno[3,4-d]thiazole) (PHVTT)). With the aim of exploring the utility of low bandgap polymers, we have carried out the interaction studies of the polymer with the ILs and investigated the behavior of polymer in the presence of ILs as the function of temperature. Recently, ILs have attracted extensive attention in polymer sciences. In this work, we have studied the temperature dependent interactions between the protic IL (1-methylimidazolium chloride ([Mim]Cl) from imidazolium family) and aprotic ILs (tributylmethylammonium methyl sulfate ([N1444][MeSO 4]) from ammonium family and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) from imidazolium family) with a low bandgap polymer. Our experimental data of UV-vis spectroscopy, photoluminescence (PL) spectroscopy, FT-IR spectroscopy, density (ρ) and speed of sound (u) as a function of temperature from 25 to 40 C with the interval of 5 C, clearly reveal that even at high temperature, [Bmim]Cl interacts strongly with the polymer as compared to other studied ILs.

UR - http://www.scopus.com/inward/record.url?scp=84893594708&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84893594708&partnerID=8YFLogxK

U2 - 10.1016/j.tca.2013.12.022

DO - 10.1016/j.tca.2013.12.022

M3 - Article

AN - SCOPUS:84893594708

SN - 0040-6031

VL - 579

SP - 15

EP - 21

JO - Thermochimica Acta

JF - Thermochimica Acta

ER -

Effect of temperature on the interactions between low bandgap polymer and ionic liquids

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this