Effect of surface molecular motion on wetting properties of poly (fluoroalkyl methacrylate) thin films

Koji Honda; Masamichi Morita; Sono Sasaki; Osami Sakata; Atsushi Takahara

Effect of surface molecular motion on wetting properties of poly (fluoroalkyl methacrylate) thin films

Koji Honda, Masamichi Morita, Sono Sasaki, Osami Sakata, Atsushi Takahara

Department of Applied Molecular Chemistry

Research output: Contribution to conference › Paper › peer-review

Abstract

Effect of surface molecular motion on wetting properties of poly(fluoroalkyl methacrylate)s with short R_f groups [PFMA-C _y, where y is fluoromethylane number in R_f groups, y = 1,2,4] thin films were characterized by dynamic contact angle measurement, X-ray photoelectron spectroscopy (XPS), wide-angle X-ray diffraction, and lateral force microscopy (LFM). The receding contact angle of PFMA-C_y was lager than poly(fluoroalkyl acry late) with short R_f groups [PFA-C]. X-ray diffraction revealed that R_f groups were not crystallized. These results indicated that the thermal molecular motion of molecular chains were restricted by α-methyl groups and the reorientation of short R _f chains was hard to occur.

Original language	English
Pages	4253-4254
Number of pages	2
Publication status	Published - 2006
Event	55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan Duration: Sept 20 2006 → Sept 22 2006

Other

Other	55th Society of Polymer Science Japan Symposium on Macromolecules
Country/Territory	Japan
City	Toyama
Period	9/20/06 → 9/22/06

All Science Journal Classification (ASJC) codes

Engineering(all)

Cite this

@conference{1f32f309b41746b6b498890abe400bda,

title = "Effect of surface molecular motion on wetting properties of poly (fluoroalkyl methacrylate) thin films",

abstract = "Effect of surface molecular motion on wetting properties of poly(fluoroalkyl methacrylate)s with short Rf groups [PFMA-C y, where y is fluoromethylane number in Rf groups, y = 1,2,4] thin films were characterized by dynamic contact angle measurement, X-ray photoelectron spectroscopy (XPS), wide-angle X-ray diffraction, and lateral force microscopy (LFM). The receding contact angle of PFMA-Cy was lager than poly(fluoroalkyl acry late) with short Rf groups [PFA-C]. X-ray diffraction revealed that Rf groups were not crystallized. These results indicated that the thermal molecular motion of molecular chains were restricted by α-methyl groups and the reorientation of short R f chains was hard to occur.",

author = "Koji Honda and Masamichi Morita and Sono Sasaki and Osami Sakata and Atsushi Takahara",

year = "2006",

language = "English",

pages = "4253--4254",

note = "55th Society of Polymer Science Japan Symposium on Macromolecules ; Conference date: 20-09-2006 Through 22-09-2006",

}

TY - CONF

T1 - Effect of surface molecular motion on wetting properties of poly (fluoroalkyl methacrylate) thin films

AU - Honda, Koji

AU - Morita, Masamichi

AU - Sasaki, Sono

AU - Sakata, Osami

AU - Takahara, Atsushi

PY - 2006

Y1 - 2006

N2 - Effect of surface molecular motion on wetting properties of poly(fluoroalkyl methacrylate)s with short Rf groups [PFMA-C y, where y is fluoromethylane number in Rf groups, y = 1,2,4] thin films were characterized by dynamic contact angle measurement, X-ray photoelectron spectroscopy (XPS), wide-angle X-ray diffraction, and lateral force microscopy (LFM). The receding contact angle of PFMA-Cy was lager than poly(fluoroalkyl acry late) with short Rf groups [PFA-C]. X-ray diffraction revealed that Rf groups were not crystallized. These results indicated that the thermal molecular motion of molecular chains were restricted by α-methyl groups and the reorientation of short R f chains was hard to occur.

AB - Effect of surface molecular motion on wetting properties of poly(fluoroalkyl methacrylate)s with short Rf groups [PFMA-C y, where y is fluoromethylane number in Rf groups, y = 1,2,4] thin films were characterized by dynamic contact angle measurement, X-ray photoelectron spectroscopy (XPS), wide-angle X-ray diffraction, and lateral force microscopy (LFM). The receding contact angle of PFMA-Cy was lager than poly(fluoroalkyl acry late) with short Rf groups [PFA-C]. X-ray diffraction revealed that Rf groups were not crystallized. These results indicated that the thermal molecular motion of molecular chains were restricted by α-methyl groups and the reorientation of short R f chains was hard to occur.

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UR - http://www.scopus.com/inward/citedby.url?scp=33846165077&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33846165077

SP - 4253

EP - 4254

T2 - 55th Society of Polymer Science Japan Symposium on Macromolecules

Y2 - 20 September 2006 through 22 September 2006

ER -

Effect of surface molecular motion on wetting properties of poly (fluoroalkyl methacrylate) thin films

Abstract

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All Science Journal Classification (ASJC) codes

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