Effect of Pr doping on catalytic properties of oxide ion conductor, Zr-Nd-O, for soot oxidation

Takashi Baba; Tomoya Takizawa; Koichiro Harada; Hiroshi Yamada; Tatsumi Ishihara; Akihide Takami

doi:10.1016/j.cattod.2014.10.041

Effect of Pr doping on catalytic properties of oxide ion conductor, Zr-Nd-O, for soot oxidation

Takashi Baba, Tomoya Takizawa, Koichiro Harada, Hiroshi Yamada, Tatsumi Ishihara, Akihide Takami

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Effects of incorporation of Pr into Zr-Nd oxides possessing high oxide ion conductivity on catalytic soot oxidation have been investigated. In carbon oxidation under isotopic oxygen flow, Pr doping facilitates desorption of active lattice oxygen via oxygen exchange reaction, and this improves the carbon oxidation rate. Redox reaction of incorporated Pr (Pr⁴⁺ to Pr³⁺) hardly occurs under both reductive and oxidative conditions. Pr doping presents mixed hole and oxide-ion conductivity, and the hole conduction becomes more dominant with increasing Pr content. Therefore, the generation of electron hole in the oxygen incorporation step and its recombining with electron in the oxygen desorption step seems to enhance the participation of active lattice oxygen in carbon oxidation and improve the catalytic oxidation performance.

Original language	English
Pages (from-to)	2-6
Number of pages	5
Journal	Catalysis Today
Volume	251
DOIs	https://doi.org/10.1016/j.cattod.2014.10.041
Publication status	Published - Aug 1 2015

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1016/j.cattod.2014.10.041

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title = "Effect of Pr doping on catalytic properties of oxide ion conductor, Zr-Nd-O, for soot oxidation",

abstract = "Effects of incorporation of Pr into Zr-Nd oxides possessing high oxide ion conductivity on catalytic soot oxidation have been investigated. In carbon oxidation under isotopic oxygen flow, Pr doping facilitates desorption of active lattice oxygen via oxygen exchange reaction, and this improves the carbon oxidation rate. Redox reaction of incorporated Pr (Pr4+ to Pr3+) hardly occurs under both reductive and oxidative conditions. Pr doping presents mixed hole and oxide-ion conductivity, and the hole conduction becomes more dominant with increasing Pr content. Therefore, the generation of electron hole in the oxygen incorporation step and its recombining with electron in the oxygen desorption step seems to enhance the participation of active lattice oxygen in carbon oxidation and improve the catalytic oxidation performance.",

author = "Takashi Baba and Tomoya Takizawa and Koichiro Harada and Hiroshi Yamada and Tatsumi Ishihara and Akihide Takami",

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T1 - Effect of Pr doping on catalytic properties of oxide ion conductor, Zr-Nd-O, for soot oxidation

AU - Baba, Takashi

AU - Takizawa, Tomoya

AU - Harada, Koichiro

AU - Yamada, Hiroshi

AU - Ishihara, Tatsumi

AU - Takami, Akihide

PY - 2015/8/1

Y1 - 2015/8/1

N2 - Effects of incorporation of Pr into Zr-Nd oxides possessing high oxide ion conductivity on catalytic soot oxidation have been investigated. In carbon oxidation under isotopic oxygen flow, Pr doping facilitates desorption of active lattice oxygen via oxygen exchange reaction, and this improves the carbon oxidation rate. Redox reaction of incorporated Pr (Pr4+ to Pr3+) hardly occurs under both reductive and oxidative conditions. Pr doping presents mixed hole and oxide-ion conductivity, and the hole conduction becomes more dominant with increasing Pr content. Therefore, the generation of electron hole in the oxygen incorporation step and its recombining with electron in the oxygen desorption step seems to enhance the participation of active lattice oxygen in carbon oxidation and improve the catalytic oxidation performance.

AB - Effects of incorporation of Pr into Zr-Nd oxides possessing high oxide ion conductivity on catalytic soot oxidation have been investigated. In carbon oxidation under isotopic oxygen flow, Pr doping facilitates desorption of active lattice oxygen via oxygen exchange reaction, and this improves the carbon oxidation rate. Redox reaction of incorporated Pr (Pr4+ to Pr3+) hardly occurs under both reductive and oxidative conditions. Pr doping presents mixed hole and oxide-ion conductivity, and the hole conduction becomes more dominant with increasing Pr content. Therefore, the generation of electron hole in the oxygen incorporation step and its recombining with electron in the oxygen desorption step seems to enhance the participation of active lattice oxygen in carbon oxidation and improve the catalytic oxidation performance.

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Effect of Pr doping on catalytic properties of oxide ion conductor, Zr-Nd-O, for soot oxidation

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