Doubly N-fused porphyrin

Motoki Toganoh; Tomoyuki Kimura; Hidemitsu Uno; Hiroyuki Furuta

doi:10.1002/anie.200803670

Doubly N-fused porphyrin

Motoki Toganoh, Tomoyuki Kimura, Hidemitsu Uno, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

(Figure Presented) Are you N-fused? Doubly N-fused porphyrin (see picture; Br red, F green, N blue) exhibits exceptionally long-wavelength absorption for an 18π aromatic system (in excess of 1600 nm). The HOMO-LUMO energy gap of doubly N-fused porphyrin is extremely small for an [18]annulenic compound and results from endocyclic extension of the porphyrin π system.

Original language	English
Pages (from-to)	8913-8916
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	46
DOIs	https://doi.org/10.1002/anie.200803670
Publication status	Published - Nov 3 2008

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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abstract = "(Figure Presented) Are you N-fused? Doubly N-fused porphyrin (see picture; Br red, F green, N blue) exhibits exceptionally long-wavelength absorption for an 18π aromatic system (in excess of 1600 nm). The HOMO-LUMO energy gap of doubly N-fused porphyrin is extremely small for an [18]annulenic compound and results from endocyclic extension of the porphyrin π system.",

author = "Motoki Toganoh and Tomoyuki Kimura and Hidemitsu Uno and Hiroyuki Furuta",

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AU - Toganoh, Motoki

AU - Kimura, Tomoyuki

AU - Uno, Hidemitsu

AU - Furuta, Hiroyuki

PY - 2008/11/3

Y1 - 2008/11/3

N2 - (Figure Presented) Are you N-fused? Doubly N-fused porphyrin (see picture; Br red, F green, N blue) exhibits exceptionally long-wavelength absorption for an 18π aromatic system (in excess of 1600 nm). The HOMO-LUMO energy gap of doubly N-fused porphyrin is extremely small for an [18]annulenic compound and results from endocyclic extension of the porphyrin π system.

AB - (Figure Presented) Are you N-fused? Doubly N-fused porphyrin (see picture; Br red, F green, N blue) exhibits exceptionally long-wavelength absorption for an 18π aromatic system (in excess of 1600 nm). The HOMO-LUMO energy gap of doubly N-fused porphyrin is extremely small for an [18]annulenic compound and results from endocyclic extension of the porphyrin π system.

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Doubly N-fused porphyrin

Abstract

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