TY - JOUR
T1 - Double-decker ferrocene-type complex of N-fused porphyrin
T2 - A model of π-extended ferrocene?
AU - Toganoh, Motoki
AU - Sato, Ayumi
AU - Furuta, Hiroyuki
N1 - Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.
PY - 2011/3/14
Y1 - 2011/3/14
N2 - Whopper sandwich: A double-decker ferrocene-type complex with N-fused porphyrinato ligands (see picture) was synthesized from N-fused porphyrin, and its structure and properties were characterized with X-ray crystallographic analysis, variable-temperature 1H NMR spectra, and electrochemical measurements. The unique three-dimensional d-π conjugated system was elucidated with the aid of DFT studies.
AB - Whopper sandwich: A double-decker ferrocene-type complex with N-fused porphyrinato ligands (see picture) was synthesized from N-fused porphyrin, and its structure and properties were characterized with X-ray crystallographic analysis, variable-temperature 1H NMR spectra, and electrochemical measurements. The unique three-dimensional d-π conjugated system was elucidated with the aid of DFT studies.
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U2 - 10.1002/anie.201007940
DO - 10.1002/anie.201007940
M3 - Article
C2 - 21387481
AN - SCOPUS:79952524335
SN - 1433-7851
VL - 50
SP - 2752
EP - 2755
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 12
ER -