Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

Suguru Yoshida; Takahisa Yano; Yoshihiro Misawa; Yasuyuki Sugimura; Kazunobu Igawa; Shigeomi Shimizu; Katsuhiko Tomooka; Takamitsu Hosoya

doi:10.1021/jacs.5b10557

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

Suguru Yoshida, Takahisa Yano, Yoshihiro Misawa, Yasuyuki Sugimura, Kazunobu Igawa, Shigeomi Shimizu, Katsuhiko Tomooka, Takamitsu Hosoya

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

109 Citations (Scopus)

Abstract

A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.

Original language	English
Pages (from-to)	14071-14074
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	44
DOIs	https://doi.org/10.1021/jacs.5b10557
Publication status	Published - Nov 11 2015

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.5b10557

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title = "Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation",

abstract = "A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.",

author = "Suguru Yoshida and Takahisa Yano and Yoshihiro Misawa and Yasuyuki Sugimura and Kazunobu Igawa and Shigeomi Shimizu and Katsuhiko Tomooka and Takamitsu Hosoya",

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AU - Yoshida, Suguru

AU - Yano, Takahisa

AU - Misawa, Yoshihiro

AU - Sugimura, Yasuyuki

AU - Igawa, Kazunobu

AU - Shimizu, Shigeomi

AU - Tomooka, Katsuhiko

AU - Hosoya, Takamitsu

PY - 2015/11/11

Y1 - 2015/11/11

N2 - A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.

AB - A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.

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Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

Abstract

All Science Journal Classification (ASJC) codes

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