Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate

Ken Sakai; Eri Ishigami; Kazuo Yokokawa; Takashi Kajiwara; Tasuku Ito

doi:10.1107/S1600536803012224

Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate

Ken Sakai, Eri Ishigami, Kazuo Yokokawa, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The title compound, [Pt₂(NH₃)₄(C ₅H₉O₂)₂](SO₄) ·H₂O, does not form an infinite chain, but has discrete dimeric cations in the crystal structure. The intradimer Pt-Pt distance in the pivalate dimer [2.9011 (9) Å] is effectively shorter than that reported for the acetate analog [2.9713 (8) Å], demonstrating the strong electron-donating property of the bridging pivalate ligand.

Original language	English
Pages (from-to)	m443-m445
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	7
DOIs	https://doi.org/10.1107/S1600536803012224
Publication status	Published - Jul 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536803012224

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title = "Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate",

abstract = "The title compound, [Pt2(NH3)4(C 5H9O2)2](SO4) ·H2O, does not form an infinite chain, but has discrete dimeric cations in the crystal structure. The intradimer Pt-Pt distance in the pivalate dimer [2.9011 (9) {\AA}] is effectively shorter than that reported for the acetate analog [2.9713 (8) {\AA}], demonstrating the strong electron-donating property of the bridging pivalate ligand.",

author = "Ken Sakai and Eri Ishigami and Kazuo Yokokawa and Takashi Kajiwara and Tasuku Ito",

year = "2003",

month = jul,

doi = "10.1107/S1600536803012224",

language = "English",

volume = "59",

pages = "m443--m445",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

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T1 - Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate

AU - Sakai, Ken

AU - Ishigami, Eri

AU - Yokokawa, Kazuo

AU - Kajiwara, Takashi

AU - Ito, Tasuku

PY - 2003/7

Y1 - 2003/7

N2 - The title compound, [Pt2(NH3)4(C 5H9O2)2](SO4) ·H2O, does not form an infinite chain, but has discrete dimeric cations in the crystal structure. The intradimer Pt-Pt distance in the pivalate dimer [2.9011 (9) Å] is effectively shorter than that reported for the acetate analog [2.9713 (8) Å], demonstrating the strong electron-donating property of the bridging pivalate ligand.

AB - The title compound, [Pt2(NH3)4(C 5H9O2)2](SO4) ·H2O, does not form an infinite chain, but has discrete dimeric cations in the crystal structure. The intradimer Pt-Pt distance in the pivalate dimer [2.9011 (9) Å] is effectively shorter than that reported for the acetate analog [2.9713 (8) Å], demonstrating the strong electron-donating property of the bridging pivalate ligand.

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U2 - 10.1107/S1600536803012224

DO - 10.1107/S1600536803012224

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SP - m443-m445

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Di-μ-pivalato-bis[cis-diammineplatinum(II)] sulfate monohydrate

Abstract

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