Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer

Mina Mizota; Ken Sakai

doi:10.1107/S1600536804006877

Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer

Mina Mizota, Ken Sakai

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In the title compound, [Pt₂(C₁₀H₈N ₂)₂(C₅H₅N₂) ₂](NO₃)₂·-4H₂O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) Å. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) Å. No metal-metal interaction exists between the dimers.

Original language	English
Pages (from-to)	m473-m476
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	4
DOIs	https://doi.org/10.1107/S1600536804006877
Publication status	Published - Apr 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer",

abstract = "In the title compound, [Pt2(C10H8N 2)2(C5H5N2) 2](NO3)2·-4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) {\AA}. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) {\AA}. No metal-metal interaction exists between the dimers.",

author = "Mina Mizota and Ken Sakai",

year = "2004",

month = apr,

doi = "10.1107/S1600536804006877",

language = "English",

volume = "60",

pages = "m473--m476",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

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T1 - Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer

AU - Mizota, Mina

AU - Sakai, Ken

PY - 2004/4

Y1 - 2004/4

N2 - In the title compound, [Pt2(C10H8N 2)2(C5H5N2) 2](NO3)2·-4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) Å. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) Å. No metal-metal interaction exists between the dimers.

AB - In the title compound, [Pt2(C10H8N 2)2(C5H5N2) 2](NO3)2·-4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt - Pt distance being 2.8724 (6) Å. The dimers form a one-dimensional stack based on π-π stacking interactions between the bpy (2,2′-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) Å. No metal-metal interaction exists between the dimers.

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JO - Acta Crystallographica Section E: Structure Reports Online

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ER -

Di-μ-2-aminopyridinato-bis[(2,2′-bipyridine)-platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer

Abstract

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