TY - JOUR
T1 - Development of paper-structured catalyst for application to direct internal reforming solid oxide fuel cell fueled by biogas
AU - Nguyen, T. G.H.
AU - Sakamoto, M.
AU - Uchida, T.
AU - Doan, D. C.T.
AU - Dang, M. C.
AU - Tu, P. H.
AU - Sasaki, K.
AU - Shiratori, Yusuke
N1 - Funding Information:
This research was supported by JICA/JST , SATREPS .
Funding Information:
This research was supported by JICA/JST, SATREPS.
Publisher Copyright:
© 2019 Hydrogen Energy Publications LLC
PY - 2019/4/23
Y1 - 2019/4/23
N2 - A flexible paper-structured catalyst (PSC) that can be applied to the anode of a solid oxide fuel cell (SOFC) was examined for its potential to enable direct internal reforming (DIR) operation. The catalytic activity of three types of Ni-loaded PSCs: (a) without the dispersion of support oxide particles in the fiber network (PSC-A), (b) with the dispersion of (Mg,Al)O derived from hydrotalcite (PSC–B), and (c) with the dispersion of (Ce,Zr)O2-δ (PSC–C), for dry reforming of CH4 was evaluated at operating temperatures of 650–800 °C. Among the PSCs, PSC-C exhibited the highest CH4 conversion with the lowest degradation rate. The electrochemical performance of an electrolyte-supported cell (ESC) was evaluated under the flow of simulated biogas at 750 °C for cases without and with the PSCs on the anode. The application of the PSCs improved the cell performance. In particular, PSC-C had a remarkably positive effect on stabilizing DIRSOFC operation fueled by biogas.
AB - A flexible paper-structured catalyst (PSC) that can be applied to the anode of a solid oxide fuel cell (SOFC) was examined for its potential to enable direct internal reforming (DIR) operation. The catalytic activity of three types of Ni-loaded PSCs: (a) without the dispersion of support oxide particles in the fiber network (PSC-A), (b) with the dispersion of (Mg,Al)O derived from hydrotalcite (PSC–B), and (c) with the dispersion of (Ce,Zr)O2-δ (PSC–C), for dry reforming of CH4 was evaluated at operating temperatures of 650–800 °C. Among the PSCs, PSC-C exhibited the highest CH4 conversion with the lowest degradation rate. The electrochemical performance of an electrolyte-supported cell (ESC) was evaluated under the flow of simulated biogas at 750 °C for cases without and with the PSCs on the anode. The application of the PSCs improved the cell performance. In particular, PSC-C had a remarkably positive effect on stabilizing DIRSOFC operation fueled by biogas.
UR - http://www.scopus.com/inward/record.url?scp=85063053847&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85063053847&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2019.02.134
DO - 10.1016/j.ijhydene.2019.02.134
M3 - Article
AN - SCOPUS:85063053847
SN - 0360-3199
VL - 44
SP - 10484
EP - 10497
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
IS - 21
ER -
