Cyclohexane-coupled bipolar host materials with high triplet energies for organic light-emitting diodes based on thermally activated delayed fluorescence

In Seob Park, Hongwook Seo, Hiroki Tachibana, Joung Uk Kim, Jinbo Zhang, Se Mo Son, Takuma Yasuda

    Research output: Contribution to journalArticlepeer-review

    26 Citations (Scopus)

    Abstract

    Thermally activated delayed fluorescence-based organic light-emitting diodes (TADF-OLEDs) have recently attracted tremendous research interest as next-generation optoelectronic devices. However, there are a limited number of host materials with an appropriately high lowest-excited triplet energy (ET) and bipolar charge transport properties for highefficiency TADF-OLEDs. Moreover, these host materials should have high thermal and morphological stabilities. In this study, we develop novel bipolar host materials consisting of an electrondonating 9-phenylcarbazole unit and an electron-Accepting triphenylphosphine oxide, triphenylphosphine sulfide, or 2,4,6-triphenyl-1,3,5-Triazine unit linked by a nonconjugated cyclohexane core. These bipolar host materials possess high glasstransition temperatures of over 100 °C and high ET values of approximately 3.0 eV. TADF-OLEDs employing these bipolar host materials could achieve high external electroluminescence quantum efficiencies of up to 21.7% together with reduced efficiency roll-off characteristics, because of expansion of the chargerecombination zone within the emission layer arising from the bipolar charge transport ability of these host materials.

    Original languageEnglish
    Pages (from-to)2693-2700
    Number of pages8
    JournalACS Applied Materials and Interfaces
    Volume9
    Issue number3
    DOIs
    Publication statusPublished - Jan 25 2017

    All Science Journal Classification (ASJC) codes

    • General Materials Science

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