Cyclodextrin-assisted synthesis of a metallosupramolecular terbium(III) polymer and its fluorescence properties and chiral recognition

Daisuke Yoshihara; Youichi Tsuchiya; Takao Noguchi; Tatsuhiro Yamamoto; Arnab Dawn; Seiji Shinkai

doi:10.1002/chem.201302138

Cyclodextrin-assisted synthesis of a metallosupramolecular terbium(III) polymer and its fluorescence properties and chiral recognition

Daisuke Yoshihara
, Youichi Tsuchiya
, Takao Noguchi
, Tatsuhiro Yamamoto
, Arnab Dawn
, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Hold and connect! Inclusion of a bridging ligand into cyclodextrin (CD), followed by the addition of Tb^III leads to a polyrotaxane-type metallosupramolecular polymer (see figure, L=4,4′-biphenyldicarboxylic acid). This polymer can recognize chirality and differentiate enantiomers by fluorescence and circular dichroism spectral changes.

Original language	English
Pages (from-to)	15485-15488
Number of pages	4
Journal	Chemistry - A European Journal
Volume	19
Issue number	46
DOIs	https://doi.org/10.1002/chem.201302138
Publication status	Published - Nov 11 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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10.1002/chem.201302138

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abstract = "Hold and connect! Inclusion of a bridging ligand into cyclodextrin (CD), followed by the addition of TbIII leads to a polyrotaxane-type metallosupramolecular polymer (see figure, L=4,4′-biphenyldicarboxylic acid). This polymer can recognize chirality and differentiate enantiomers by fluorescence and circular dichroism spectral changes.",

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AU - Yoshihara, Daisuke

AU - Tsuchiya, Youichi

AU - Noguchi, Takao

AU - Yamamoto, Tatsuhiro

AU - Dawn, Arnab

AU - Shinkai, Seiji

PY - 2013/11/11

Y1 - 2013/11/11

N2 - Hold and connect! Inclusion of a bridging ligand into cyclodextrin (CD), followed by the addition of TbIII leads to a polyrotaxane-type metallosupramolecular polymer (see figure, L=4,4′-biphenyldicarboxylic acid). This polymer can recognize chirality and differentiate enantiomers by fluorescence and circular dichroism spectral changes.

AB - Hold and connect! Inclusion of a bridging ligand into cyclodextrin (CD), followed by the addition of TbIII leads to a polyrotaxane-type metallosupramolecular polymer (see figure, L=4,4′-biphenyldicarboxylic acid). This polymer can recognize chirality and differentiate enantiomers by fluorescence and circular dichroism spectral changes.

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U2 - 10.1002/chem.201302138

DO - 10.1002/chem.201302138

M3 - Article

AN - SCOPUS:84887022359

SN - 0947-6539

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 46

ER -

Cyclodextrin-assisted synthesis of a metallosupramolecular terbium(III) polymer and its fluorescence properties and chiral recognition

Abstract

All Science Journal Classification (ASJC) codes

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