Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K

Chunhua Ge; Hui Zhong Kou; Zhong Hai Ni; Yun Bo Jiang; Li Fang Zhang; Ai Li Cui; Osamu Sato

doi:10.1246/cl.2005.1280

Cyano-bridged one-dimensional Sm ^III-Fe ^III molecule-based magnet with an ordering temperature of 3.4 K

Chunhua Ge, Hui Zhong Kou, Zhong Hai Ni, Yun Bo Jiang, Li Fang Zhang, Ai Li Cui, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

A new cynao-bridged Sm ^III-Fe ^III bimetallic coordination polymer has been prepared by the reaction of (n-Bu ₄N) ₃Fe(CN) ₆ and Sm(NO ₃) ₃·6H ₂O in a DMF-H ₂O media. The complex consists of alternate Sm(DMF) ₄(H ₂O) ₂ and Fe(CN) ₆ units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with T _c = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.

Original language	English
Article number	CL-050881
Pages (from-to)	1280-1281
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	9
DOIs	https://doi.org/10.1246/cl.2005.1280
Publication status	Published - Sept 5 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)

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title = "Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K",

abstract = "A new cynao-bridged Sm III-Fe III bimetallic coordination polymer has been prepared by the reaction of (n-Bu 4N) 3Fe(CN) 6 and Sm(NO 3) 3·6H 2O in a DMF-H 2O media. The complex consists of alternate Sm(DMF) 4(H 2O) 2 and Fe(CN) 6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with T c = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.",

author = "Chunhua Ge and Kou, {Hui Zhong} and Ni, {Zhong Hai} and Jiang, {Yun Bo} and Zhang, {Li Fang} and Cui, {Ai Li} and Osamu Sato",

year = "2005",

month = sep,

day = "5",

doi = "10.1246/cl.2005.1280",

language = "English",

volume = "34",

pages = "1280--1281",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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T1 - Cyano-bridged one-dimensional Sm III-Fe III molecule-based magnet with an ordering temperature of 3.4 K

AU - Ge, Chunhua

AU - Kou, Hui Zhong

AU - Ni, Zhong Hai

AU - Jiang, Yun Bo

AU - Zhang, Li Fang

AU - Cui, Ai Li

AU - Sato, Osamu

PY - 2005/9/5

Y1 - 2005/9/5

N2 - A new cynao-bridged Sm III-Fe III bimetallic coordination polymer has been prepared by the reaction of (n-Bu 4N) 3Fe(CN) 6 and Sm(NO 3) 3·6H 2O in a DMF-H 2O media. The complex consists of alternate Sm(DMF) 4(H 2O) 2 and Fe(CN) 6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with T c = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.

AB - A new cynao-bridged Sm III-Fe III bimetallic coordination polymer has been prepared by the reaction of (n-Bu 4N) 3Fe(CN) 6 and Sm(NO 3) 3·6H 2O in a DMF-H 2O media. The complex consists of alternate Sm(DMF) 4(H 2O) 2 and Fe(CN) 6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with T c = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.

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JO - Chemistry Letters

JF - Chemistry Letters

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ER -

Cyano-bridged one-dimensional Sm ^III-Fe ^III molecule-based magnet with an ordering temperature of 3.4 K

Abstract

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