Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

Benjamin Le Ouay; Haruka Yoshino; Kenta Sasaki; Yuta Ohtsubo; Ryo Ohtani; Masaaki Ohba

doi:10.1039/d1cc01185e

Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

Benjamin Le Ouay, Haruka Yoshino, Kenta Sasaki, Yuta Ohtsubo, Ryo Ohtani, Masaaki Ohba

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.

Original language	English
Pages (from-to)	5187-5190
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	42
DOIs	https://doi.org/10.1039/d1cc01185e
Publication status	Published - May 25 2021

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d1cc01185e

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title = "Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates",

abstract = "Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.",

author = "{Le Ouay}, Benjamin and Haruka Yoshino and Kenta Sasaki and Yuta Ohtsubo and Ryo Ohtani and Masaaki Ohba",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number JP16H06519 (Coordination Asymmetry), JP18H01997, JP18K14245, JP19H04701 and JP20K22554. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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T1 - Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

AU - Le Ouay, Benjamin

AU - Yoshino, Haruka

AU - Sasaki, Kenta

AU - Ohtsubo, Yuta

AU - Ohtani, Ryo

AU - Ohba, Masaaki

N1 - Funding Information: This work was supported by JSPS KAKENHI Grant Number JP16H06519 (Coordination Asymmetry), JP18H01997, JP18K14245, JP19H04701 and JP20K22554. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/5/25

Y1 - 2021/5/25

N2 - Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.

AB - Charge-driven self-assembly of cationic zirconium-based metal-organic polyhedra (MOPs) with polyoxometalates (POMs) leads to a series of porous crystalline salts, prepared by simple mixing of soluble precursors. The reactivity of immobilized POMs was greatly increased, as demonstrated by their fast reduction by hydrazine vapors, without loss of structural integrity.

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JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Crystalline assembly of metal-organic polyhedra driven by ionic interactions with polyoxometalates

Abstract

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