Crystal structure of new compounds, Cu6O8Cu2X (X = Cl, No3)

Hiroshi Hayakawa; Etsuo Akiba; Hideo Ihara; Shuitiro Ono

doi:10.1143/JJAP.30.L1303

Crystal structure of new compounds, Cu₆O₈Cu₂X (X = Cl, No₃)

Hiroshi Hayakawa, Etsuo Akiba, Hideo Ihara, Shuitiro Ono

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6 Citations (Scopus)

Abstract

Crystal structure analyses of new compounds, Cu₆O₈Cu₂X (X = Cl, NO₃), have been carried out using the X-ray powder pattern fitting method (Rietveld method) together with thermal analyses. Although these compounds have a face-centered cubic structure analogous to that of Cu₆OgInCl previously reported with a space group of Fm3m, the Cu₂ (24e site) ions have a quite different configuration from that of the corresponding In ion. From the results of the above- mentioned analyses together with chemical analyses, the compositions of these samples were obtained as Cu_5.7 O₈Cu_1.9Cl_0.69(NO₃)_0.31 and CCu_5.7 O₈Cu_1.9Cl_0.69NO₃respectively. The unit cell parameters are a = 9.376(1) Å for the former and 9.481(1) Å for the latter. These compounds decompose to CuO at 400°C and 350°C, respectively.

Original language	English
Pages (from-to)	1303-1306
Number of pages	4
Journal	Japanese journal of applied physics
Volume	30
Issue number	7
DOIs	https://doi.org/10.1143/JJAP.30.L1303
Publication status	Published - Jul 1991
Externally published	Yes

All Science Journal Classification (ASJC) codes

Engineering(all)
Physics and Astronomy(all)

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10.1143/JJAP.30.L1303

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title = "Crystal structure of new compounds, Cu6O8Cu2X (X = Cl, No3)",

abstract = "Crystal structure analyses of new compounds, Cu6O8Cu2X (X = Cl, NO3), have been carried out using the X-ray powder pattern fitting method (Rietveld method) together with thermal analyses. Although these compounds have a face-centered cubic structure analogous to that of Cu6OgInCl previously reported with a space group of Fm3m, the Cu2 (24e site) ions have a quite different configuration from that of the corresponding In ion. From the results of the above- mentioned analyses together with chemical analyses, the compositions of these samples were obtained as Cu5.7 O8Cu1.9Cl0.69(NO3)0.31 and CCu5.7 O8Cu1.9Cl0.69NO3respectively. The unit cell parameters are a = 9.376(1) {\AA} for the former and 9.481(1) {\AA} for the latter. These compounds decompose to CuO at 400°C and 350°C, respectively.",

author = "Hiroshi Hayakawa and Etsuo Akiba and Hideo Ihara and Shuitiro Ono",

year = "1991",

month = jul,

doi = "10.1143/JJAP.30.L1303",

language = "English",

volume = "30",

pages = "1303--1306",

journal = "Japanese journal of applied physics",

issn = "0021-4922",

publisher = "The Japan Society of Applied Physics",

number = "7",

}

TY - JOUR

T1 - Crystal structure of new compounds, Cu6O8Cu2X (X = Cl, No3)

AU - Hayakawa, Hiroshi

AU - Akiba, Etsuo

AU - Ihara, Hideo

AU - Ono, Shuitiro

PY - 1991/7

Y1 - 1991/7

N2 - Crystal structure analyses of new compounds, Cu6O8Cu2X (X = Cl, NO3), have been carried out using the X-ray powder pattern fitting method (Rietveld method) together with thermal analyses. Although these compounds have a face-centered cubic structure analogous to that of Cu6OgInCl previously reported with a space group of Fm3m, the Cu2 (24e site) ions have a quite different configuration from that of the corresponding In ion. From the results of the above- mentioned analyses together with chemical analyses, the compositions of these samples were obtained as Cu5.7 O8Cu1.9Cl0.69(NO3)0.31 and CCu5.7 O8Cu1.9Cl0.69NO3respectively. The unit cell parameters are a = 9.376(1) Å for the former and 9.481(1) Å for the latter. These compounds decompose to CuO at 400°C and 350°C, respectively.

AB - Crystal structure analyses of new compounds, Cu6O8Cu2X (X = Cl, NO3), have been carried out using the X-ray powder pattern fitting method (Rietveld method) together with thermal analyses. Although these compounds have a face-centered cubic structure analogous to that of Cu6OgInCl previously reported with a space group of Fm3m, the Cu2 (24e site) ions have a quite different configuration from that of the corresponding In ion. From the results of the above- mentioned analyses together with chemical analyses, the compositions of these samples were obtained as Cu5.7 O8Cu1.9Cl0.69(NO3)0.31 and CCu5.7 O8Cu1.9Cl0.69NO3respectively. The unit cell parameters are a = 9.376(1) Å for the former and 9.481(1) Å for the latter. These compounds decompose to CuO at 400°C and 350°C, respectively.

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JO - Japanese journal of applied physics

JF - Japanese journal of applied physics

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ER -

Crystal structure of new compounds, Cu₆O₈Cu₂X (X = Cl, No₃)

Abstract

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