A simple method for estimating the Wilson parameters from pure component properties alone previously proposed has been adopted to predict the vapor-liquid equilibria of binary systems containing carboxylic acids such as acetic acid. Carboxylic acid vapors are characterized by the presence of large amounts of dimers. The binary mixtures of non-associating substancecarboxylic acid and carboxylic acidcarboxylic acid have been studied. The prediction performances obtained are examined and discussed.
All Science Journal Classification (ASJC) codes
- General Chemical Engineering
- General Chemistry