TY - JOUR
T1 - Cooperative spin transition and thermally quenched high-spin state in new polymorph of [Fe(qsal) 2]I 3
AU - Takahashi, Kazuyuki
AU - Sato, Tetsuya
AU - Mori, Hatsumi
AU - Tajima, Hiroyuki
AU - Einaga, Yasuaki
AU - Sato, Osamu
N1 - Funding Information:
Acknowledgements This work was partly supported by a Grant-in-Aid for Scientific Research on Innovative Areas of Molecular Degrees of Freedom (No. 20110007), and a Grant-in-Aid for Young Scientists (B) (No. 19750107) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan.
PY - 2012/3
Y1 - 2012/3
N2 - Novel polymorph of the ferric spin crossover complex, β-[Fe(qsal) 2]I 3 [qsalH = N-(8-quinolyl)salicylaldimine], has been prepared and characterized by magnetic susceptibilities and Mössbauer spectra. β polymorph exhibited a cooperative complete spin transition with a thermal hysteresis of 25 K and a tendency to be quenched in the high-spin (HS) state, which is contrastive to a gradual incomplete spin conversion in α polymorph.
AB - Novel polymorph of the ferric spin crossover complex, β-[Fe(qsal) 2]I 3 [qsalH = N-(8-quinolyl)salicylaldimine], has been prepared and characterized by magnetic susceptibilities and Mössbauer spectra. β polymorph exhibited a cooperative complete spin transition with a thermal hysteresis of 25 K and a tendency to be quenched in the high-spin (HS) state, which is contrastive to a gradual incomplete spin conversion in α polymorph.
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U2 - 10.1007/s10751-011-0497-z
DO - 10.1007/s10751-011-0497-z
M3 - Article
AN - SCOPUS:84859612585
SN - 0304-3843
VL - 206
SP - 1
EP - 5
JO - Hyperfine Interactions
JF - Hyperfine Interactions
IS - 1-3
ER -