Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations

Shigefumi Kanchiku; Hidehiro Suematsu; Kazuhiro Matsumoto; Tatsuya Uchida; Tsutomu Katsuki

doi:10.1002/anie.200604385

Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations

Shigefumi Kanchiku, Hidehiro Suematsu, Kazuhiro Matsumoto, Tatsuya Uchida, Tsutomu Katsuki

Division for Experimental Natural Science

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

(Chemical Equation Presented) Ringing the changes: Iridium(lll)-salen complexes 1 bearing a σ-coordinated aryl ligand (L = CH₃C ₆H₄, C₆H₅) at the apical position are found to efficiently catalyze the cis- and enantioselective cyclopropanation of mono- and disubstituted olefins (see scheme).

Original language	English
Pages (from-to)	3889-3891
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	21
DOIs	https://doi.org/10.1002/anie.200604385
Publication status	Published - 2007

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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abstract = "(Chemical Equation Presented) Ringing the changes: Iridium(lll)-salen complexes 1 bearing a σ-coordinated aryl ligand (L = CH3C 6H4, C6H5) at the apical position are found to efficiently catalyze the cis- and enantioselective cyclopropanation of mono- and disubstituted olefins (see scheme).",

author = "Shigefumi Kanchiku and Hidehiro Suematsu and Kazuhiro Matsumoto and Tatsuya Uchida and Tsutomu Katsuki",

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AU - Kanchiku, Shigefumi

AU - Suematsu, Hidehiro

AU - Matsumoto, Kazuhiro

AU - Uchida, Tatsuya

AU - Katsuki, Tsutomu

PY - 2007

Y1 - 2007

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Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations

Abstract

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