Conformational effect of silica-supported poly(octadecyl acrylate) on molecular-shape selectivity of polycyclic aromatic hydrocarbons in RP-HPLC

Makoto Takafuji; Megumi Fukui; Hamid R. Ansarian; Mahnaz Derakhshan; Atsuomi Shundo; Hirotaka Ihara

doi:10.2116/analsci.20.1681

Conformational effect of silica-supported poly(octadecyl acrylate) on molecular-shape selectivity of polycyclic aromatic hydrocarbons in RP-HPLC

Makoto Takafuji, Megumi Fukui, Hamid R. Ansarian, Mahnaz Derakhshan, Atsuomi Shundo, Hirotaka Ihara

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Poly(octadecyl acrylate) with a terminal reactive group was synthesized by radical telomerization in various solvents. The polymers were grafted onto porous silica for use in RP-HPLC, and the molecular recognition ability was investigated along with the selectivity for the structural isomers of polycyclic aromatic hydrocarbons. The mechanism of selectivity was also investigated with differential scanning calorimetry and NMR spectroscopic observations.

Original language	English
Pages (from-to)	1681-1685
Number of pages	5
Journal	analytical sciences
Volume	20
Issue number	12
DOIs	https://doi.org/10.2116/analsci.20.1681
Publication status	Published - Dec 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Analytical Chemistry

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abstract = "Poly(octadecyl acrylate) with a terminal reactive group was synthesized by radical telomerization in various solvents. The polymers were grafted onto porous silica for use in RP-HPLC, and the molecular recognition ability was investigated along with the selectivity for the structural isomers of polycyclic aromatic hydrocarbons. The mechanism of selectivity was also investigated with differential scanning calorimetry and NMR spectroscopic observations.",

author = "Makoto Takafuji and Megumi Fukui and Ansarian, {Hamid R.} and Mahnaz Derakhshan and Atsuomi Shundo and Hirotaka Ihara",

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AU - Takafuji, Makoto

AU - Fukui, Megumi

AU - Ansarian, Hamid R.

AU - Derakhshan, Mahnaz

AU - Shundo, Atsuomi

AU - Ihara, Hirotaka

PY - 2004/12

Y1 - 2004/12

N2 - Poly(octadecyl acrylate) with a terminal reactive group was synthesized by radical telomerization in various solvents. The polymers were grafted onto porous silica for use in RP-HPLC, and the molecular recognition ability was investigated along with the selectivity for the structural isomers of polycyclic aromatic hydrocarbons. The mechanism of selectivity was also investigated with differential scanning calorimetry and NMR spectroscopic observations.

AB - Poly(octadecyl acrylate) with a terminal reactive group was synthesized by radical telomerization in various solvents. The polymers were grafted onto porous silica for use in RP-HPLC, and the molecular recognition ability was investigated along with the selectivity for the structural isomers of polycyclic aromatic hydrocarbons. The mechanism of selectivity was also investigated with differential scanning calorimetry and NMR spectroscopic observations.

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ER -

Conformational effect of silica-supported poly(octadecyl acrylate) on molecular-shape selectivity of polycyclic aromatic hydrocarbons in RP-HPLC

Abstract

All Science Journal Classification (ASJC) codes

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