Confirmation of a sulfur-rich layer on pyrite after oxidative dissolution by Fe(lIl) ions around pH2

Keiko Sasaki; Masami Tsunekawa; Toshiaki Ohtsuka; Hidetaka Konno

doi:10.1016/0016-7037(95)00203-C

Confirmation of a sulfur-rich layer on pyrite after oxidative dissolution by Fe(lIl) ions around pH2

Keiko Sasaki, Masami Tsunekawa, Toshiaki Ohtsuka, Hidetaka Konno

Research output: Contribution to journal › Article › peer-review

104 Citations (Scopus)

Abstract

The stoichiometry of pyrite dissolution by Fe(II) ions was studied in chloride media around pH 2. Pyrite was found to dissolve nonstoichiometrically during the initial tens of hours and a S-rich layer was formed on the pyrite due to preferential dissolution of iron. The major constituent of the layer was elemental S, identified by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy.

Original language	English
Pages (from-to)	3155-3158
Number of pages	4
Journal	Geochimica et Cosmochimica Acta
Volume	59
Issue number	15
DOIs	https://doi.org/10.1016/0016-7037(95)00203-C
Publication status	Published - Aug 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Geochemistry and Petrology

Access to Document

10.1016/0016-7037(95)00203-C

Cite this

@article{a9d56d8e90084b968c68d1df868641b7,

title = "Confirmation of a sulfur-rich layer on pyrite after oxidative dissolution by Fe(lIl) ions around pH2",

abstract = "The stoichiometry of pyrite dissolution by Fe(II) ions was studied in chloride media around pH 2. Pyrite was found to dissolve nonstoichiometrically during the initial tens of hours and a S-rich layer was formed on the pyrite due to preferential dissolution of iron. The major constituent of the layer was elemental S, identified by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy.",

author = "Keiko Sasaki and Masami Tsunekawa and Toshiaki Ohtsuka and Hidetaka Konno",

year = "1995",

month = aug,

doi = "10.1016/0016-7037(95)00203-C",

language = "English",

volume = "59",

pages = "3155--3158",

journal = "Geochimica et Cosmochimica Acta",

issn = "0016-7037",

publisher = "Elsevier Limited",

number = "15",

}

TY - JOUR

T1 - Confirmation of a sulfur-rich layer on pyrite after oxidative dissolution by Fe(lIl) ions around pH2

AU - Sasaki, Keiko

AU - Tsunekawa, Masami

AU - Ohtsuka, Toshiaki

AU - Konno, Hidetaka

PY - 1995/8

Y1 - 1995/8

N2 - The stoichiometry of pyrite dissolution by Fe(II) ions was studied in chloride media around pH 2. Pyrite was found to dissolve nonstoichiometrically during the initial tens of hours and a S-rich layer was formed on the pyrite due to preferential dissolution of iron. The major constituent of the layer was elemental S, identified by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy.

AB - The stoichiometry of pyrite dissolution by Fe(II) ions was studied in chloride media around pH 2. Pyrite was found to dissolve nonstoichiometrically during the initial tens of hours and a S-rich layer was formed on the pyrite due to preferential dissolution of iron. The major constituent of the layer was elemental S, identified by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy.

UR - http://www.scopus.com/inward/record.url?scp=0029472895&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0029472895&partnerID=8YFLogxK

U2 - 10.1016/0016-7037(95)00203-C

DO - 10.1016/0016-7037(95)00203-C

M3 - Article

AN - SCOPUS:0029472895

SN - 0016-7037

VL - 59

SP - 3155

EP - 3158

JO - Geochimica et Cosmochimica Acta

JF - Geochimica et Cosmochimica Acta

IS - 15

ER -

Confirmation of a sulfur-rich layer on pyrite after oxidative dissolution by Fe(lIl) ions around pH2

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this